Indian Journal of Science and Technology

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Synthesis and Spectral Investigation of some Zn (II), Hg (II), Co (II) and Cu (II) Schiff Base Complexes


Affiliations
1 Department of Chemistry, Firoozabad Branch, Islamic Azad University, Firoozabad, Iran, Islamic Republic of
2 Department of Basic Sciences, Yasouj Branch, Islamic Azad University, Yasouj, Iran, Islamic Republic of
 

Three symmetrical Schiff base ligands of N, N'-bis (2-chlorobenzylidene) ethane-1, 2-diamine (BCBEN), N,N'-bis (2- nitrobenzylidene) ethane-1,2-diamine and N,N'-bis (3-phenylallylidene)-o-phenylenediamine and some zinc (II), mercury (II), cobalt (II) and copper (II) complexes were synthesized and characterized by elemental analyses, 1H NMR, 13C NMR, FT-IR, UV-Visible spectra, and molar conductance. All compounds were found to be non-electrolytes in the dimethylsulfoxide solutions.

Keywords

Schiff Base Complex, Thiocyanate, Spectral, Symmetrical
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  • Synthesis and Spectral Investigation of some Zn (II), Hg (II), Co (II) and Cu (II) Schiff Base Complexes

Abstract Views: 495  |  PDF Views: 147

Authors

A. Rahmani
Department of Chemistry, Firoozabad Branch, Islamic Azad University, Firoozabad, Iran, Islamic Republic of
E. Mahmoodabadi
Department of Chemistry, Firoozabad Branch, Islamic Azad University, Firoozabad, Iran, Islamic Republic of
B. Heidari
Department of Chemistry, Firoozabad Branch, Islamic Azad University, Firoozabad, Iran, Islamic Republic of
M. Montazerozohori
Department of Basic Sciences, Yasouj Branch, Islamic Azad University, Yasouj, Iran, Islamic Republic of
S. Joohari
Department of Basic Sciences, Yasouj Branch, Islamic Azad University, Yasouj, Iran, Islamic Republic of

Abstract


Three symmetrical Schiff base ligands of N, N'-bis (2-chlorobenzylidene) ethane-1, 2-diamine (BCBEN), N,N'-bis (2- nitrobenzylidene) ethane-1,2-diamine and N,N'-bis (3-phenylallylidene)-o-phenylenediamine and some zinc (II), mercury (II), cobalt (II) and copper (II) complexes were synthesized and characterized by elemental analyses, 1H NMR, 13C NMR, FT-IR, UV-Visible spectra, and molar conductance. All compounds were found to be non-electrolytes in the dimethylsulfoxide solutions.

Keywords


Schiff Base Complex, Thiocyanate, Spectral, Symmetrical

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DOI: https://doi.org/10.17485/ijst%2F2011%2Fv4i11%2F30259