Open Access Open Access  Restricted Access Subscription Access

Mineral Analysis of Coastal Sediment Samples of Tuna, Gujarat, India


Affiliations
1 PG & Research Dept. of Physics, Govt. Arts College, Tiruvanamalai-606601, TN, India
2 Dept. of Physics, University College of Engg., Arani-632317, TN, India
3 Dept. of Physics, St.Joseph’s College of Engg., Chennai-119, TN, India
4 Department of Physics, Sacred Heart College, Thirupattur-635601, TN, India
5 National Institute of Ocean Technology, Pallikaranai, Chennai -601302,TN, India
 

Qualitative analysis was carried out to determine the major and minor constituent minerals present in sediment samples collected at the coastal area of Tuna, Gujarat by FT-IR and XRD technique. From the IR absorption band or the locations of the different peaks, the minerals were identified with the available literature. In addition to the band positions, the sharpness or diffuseness of bands was helpful in the identification of mineral components. The IR study on sediment samples was highly useful in identifying the various minerals in sediments. Further, the representative sediment samples were analyzed by XRD technique to yield more information about the minerals. Both of these methods were non-destructive and can be used in the identification of mineralogical composition. These results confirmed that the applied techniques are relatively quicker and more reliable in mineral analysis.

Keywords

Sediment Samples, Mineral Analysis, FT-IR, XRD Technique
User

  • Adler HH and Kerr PF (1962) Infrared spectra symmetry and structure relations of some carbonate minerals. Am. Min. 48, 839-853.
  • Adler HH and Kerr PF (1963) Infrared study of Aragonite and calcite. Am. Min. 47,700-717.
  • Bottcher ME, Gehlken PL and Steele, DF (1997) Characterization of inorganic and biogenic magnesian calcites by Fourier Transform infrared spectroscopy. Sol. State Ionics. 101, 1379-1385.
  • Boruah RK, Neog AK, Borah PC and Baruah GD (1999) Petrographic study of silica bearing rocks from Assam, India. Ind. J. Eng. Mat. Sci. 6, 338-341.
  • Benedetto GED, Laviano R, Sabbatini L and Zambonin PG (2002) Infrared spectroscopy in the mineralogical characterization of ancient pottery. J. Cul. Her. 3, 177–186.
  • Chester R and Elderfield H (1967) The application of infrared absorption spectroscopy to carbonate mineralogy. Sedimentology. 9, 5-21.
  • Chester R and Green RN (1968) The infrared determination of quartz in sediments and sedimentary rocks. Chem. Geo. 3, 199-212.
  • Karr C Jr (1974) Infrared and Raman spectroscopy of lunar and terrestrial Minerals, Academic press, Newyork, pp325- 358.
  • Clark RN, King TVV, Kiejwa M, Swayze GA and Verge N (1990) High spectral resolution reflectance spectra of minerals. J. Geophys. Res. 95, 12653-12657.
  • Coates JP (1977) The IR analysis of Quartz and Asbestos, Nelioth Offset Ltd., Chesham, England.
  • Crowley JK and Vergo N (1988) Near-infrared reflectance of mixtures of kaolin group minerals; use in clay. Clay Clay Minerals. 36, 310-316.
  • Farmer VC (1974) The IR Spectra of minerals, mineralogical society, London, 42, 308-320.
  • Farmer VC (1979) Infrared spectroscopy, Data hand book for clay naterials and other non metallic minerals, Ed.Van Olphen and Fripait, 1st Ed., Pergaman press, Oxford, London. pp: 285-337.
  • Ganguly J and Banerjee BK (1985) Appraisal of infrared spectra of isolated clay fractions from different soil profiles. Trans. Ind. Cer. Soc. 26, 44–46.
  • Ghosh, S.N (1978) Infrared spectra of some selected minerals, rocks and products. J. Mat. Sci. 13, 1877-1886.
  • Herzberg G (1945) Molecular spectra and molecular structure II. Infrared and Raman spectra of polyatomic molecules, D.Van Nostrant Co., Inc., New York, p178.
  • Hlavay J, Jonas K, Elek S and Inczedy J (1978) Characterization of the particle size and the crystallinity of certain minerals by infrared spectrophotometry and other instrumental methods-II. Investigation on quartz and feldspar. Clay Minerals. 26, 139-143.
  • Hunt JM and Turner DS (1953) Determination of mineral constituents of rocks by infrared spectroscopy. Anal. Chem. 25, 1169-1174.
  • Ko TH and Chu H (2005) Spectroscopic study on sorption of hydrogen sulfide by means of red soil. Spectro. Chimica. Acta. Part-A, 61, 2253–2259.
  • Lopez MCB, Martinez-Alono and Tascon JMD (2000) Mineral matter characterization in olivine stones by joint use of LTA, XRD, FT-IR and SEM-EDX. App. Spect. 54, 1712 – 1715.
  • Lyon RJP (1967) Infrared absorption spectroscopy, physical methods in determinative mineralogy. Zussman J (Ed.) Academic Press, NY. pp: 371-403.
  • Madejova and Komadel (2001) Baseline studies of the clay minerals society source clays: Infrared Methods. Clay Minerals. 49, 410-432.
  • Neog AK, Boruah RK, Sahu OP, Borah PC, Ahmed W and Boruah GD (1999) XRD and IR of Deopani clay. Asian. Chem. Letts. 3, 172-175.
  • Post JL and Noble PN (1993) The near infrared combination band frequencies of dioctahadral smectities, micas and illites. Clay Minerals. 41, 639–644.
  • Ramasamy V, Dheenathayalu M, Ponnusamy V, Murgesan S and Mullainathan S (2003) Characterization of quartz and feldspars in white granites. J. Curr. Sci. 3(1), 181-185.
  • Ramasamy V, Murgesan S and Mullainathan S (2004) Characterization of minerals and relative disturbtion of quartz in Cavery river sediments from Tamil Nadu, India-A FT-IR study. Bull. Pure Appl. Sci. 23F (1-2), 1-7.
  • Ramasamy V, Murgesan S and Mullainathan S (2004) Fourier Transform infrared analysis of some sediments from Palaru river, Tamil Nadu, India. J. Curr. Sci. 5(2), 599–601.
  • Ramasamy V, Murgesan S and Mullainathan S (2005) Distribution and characterization of minerals in Cauvery river sediments by grain size analysis-A new approach by FT-IR study. Ind. Mineralogist. 39(2), 91-107.
  • Ravisankar R, Rajalakshmi A and Manikandan (2006) Mineral characterization of soil samples in and around saltfield area, Kelambakkam, Tamil Nadu, India. Acta Ciencia Indica. 32(3), 341–346.
  • Reig FB, Adelankndo JVG and Moreno MCM (2002) FT-IR Quantitative analysis of calcium carbonate (Calcite) and Silica (Quartz) mixtures using the constant ratio method; application to geological samples. Talanta. 58, 811-815.
  • Russell JD (1987) Infrared methods, a hand book of determinative methods in clay mineralogy, Wilson MJ (Ed.), Blackie & Son Ltd, NY. pp:11-67.
  • Senthil Kumar P, Parthasarathy G, Sharma DS, Srinivasan R and Krishnamurthy P (2001) Mineralogical and geochemical study on carbonate veins of Salem-Attur fault zone, Southern India: evidence for carbonate affinity. J. Geo. Soc. Ind. 58, 15-20.
  • Tuddenham WM and Lyon RJP (1960) Infrared techniques in the identification and measurements of minerals. Anal. Chem. 32, 1630-1634.
  • Summer ME (1995) Hand book of soil science, University of Georgia, Boca Raton Hondor press, New York. 35.White JL (1971) Interpretation of infrared spectra of soil minerals. Soil Sci. 112, 22-67.
  • Xu Z, Cornilsen BC, Popko DC, Penning WD, Wood JR and Hwang JY (2001) Quantitative mineral analysis by FT-IR spectroscopy. Int. J. Vib. Spec. 5, 4-6.
  • Yariv SH and Mendelovici E (1979) The effects of degree of crystallinity on the infrared spectrum of hematite. App. Spectroscopy. 33, 410-411.

Abstract Views: 745

PDF Views: 169




  • Mineral Analysis of Coastal Sediment Samples of Tuna, Gujarat, India

Abstract Views: 745  |  PDF Views: 169

Authors

R. Ravisankar
PG & Research Dept. of Physics, Govt. Arts College, Tiruvanamalai-606601, TN, India
G. Senthilkumar
Dept. of Physics, University College of Engg., Arani-632317, TN, India
S. Kiruba
Dept. of Physics, St.Joseph’s College of Engg., Chennai-119, TN, India
A. Chandrasekaran
Department of Physics, Sacred Heart College, Thirupattur-635601, TN, India
Prince Prakash Jebakumar
National Institute of Ocean Technology, Pallikaranai, Chennai -601302,TN, India

Abstract


Qualitative analysis was carried out to determine the major and minor constituent minerals present in sediment samples collected at the coastal area of Tuna, Gujarat by FT-IR and XRD technique. From the IR absorption band or the locations of the different peaks, the minerals were identified with the available literature. In addition to the band positions, the sharpness or diffuseness of bands was helpful in the identification of mineral components. The IR study on sediment samples was highly useful in identifying the various minerals in sediments. Further, the representative sediment samples were analyzed by XRD technique to yield more information about the minerals. Both of these methods were non-destructive and can be used in the identification of mineralogical composition. These results confirmed that the applied techniques are relatively quicker and more reliable in mineral analysis.

Keywords


Sediment Samples, Mineral Analysis, FT-IR, XRD Technique

References





DOI: https://doi.org/10.17485/ijst%2F2010%2Fv3i7%2F29813