Indian Journal of Science and Technology

Open Access Open Access  Restricted Access Subscription Access

Removal of Manganese from Well-Water on Pasuruan, East Java, Indonesia using Fixed Bed Cation Exchanger and Prediction of Kinetics Adsorption


Affiliations
1 Mining Engineering Department, Adhi Tama Surabaya Institute of Technology, Surabaya, Indonesia
2 Chemical Engineering Department, Adhi Tama Surabaya Institute of Technology, Surabaya, Indonesia
 

Objectives: Testing of a cation exchanger based water treatment apparatus and an Amberlite IR 120 Na resin medium to reduce the manganese content in the well-water is proposed. Methods/Statistical Analysis: Testing was done by wellwater treatment in a fixed bed cation exchanger in continuous flow. The variables used were the resin mass and flow rate and its effect on the manganese concentration in the outflow of the equipment. Manganese content was analyzed by Atomic Absorption Spectrophotometry (AAS) method. The isothermal adsorption equation was tested by the Freundich and Langmuir equations. Findings: The result of this research showed Amberlite resin IR 120 Na adsorbed manganese ion was about 96.3-98.9%; the optimal resin mass about 20 grams with a flow rate about 0.04 L.s-1 when viewed from an economic point. Resin absorption power to manganese increases with decreasing flow rate and increasing resin mass. Freundlich equation with constant n = 0.6539 and Kf = 4.6644 with correlation coefficient 0.7957. Langmuir equation with a constant As = -0.0927 and Kb = -6.3820 with a correlation coefficient -0.4314. Application/Improvements: Cation exchanger using Amberlite IR 120 Na resin media capable of remove manganese in well-water with efficiency > 96% and resin can be regenerated again.
User

  • Stefan DS, Meghea I. Mechanism of simultaneous removal of Ca2+, Ni2+, Pb2+and Al3+ions from aqueous solutions using Purolite®S930 ion exchange resin, Comptes Rendus Chimie. 2014; 17(5):496–502. Crossref.

  • Tobiasz A, Sołtys M, Kurys E, Domagała K, DudekAdamska D, Walas S. Multicomutation flow system for manganese speciation by solid phase extraction and flame atomic absorption spectrometry, Spectrochimica Acta Part B: Atomic Spectrosccopy. 2017; 134:11–6. Crossref.

  • O’Neal SL, Hong L, Fu S, Jiang W, Jones A, Nie LH. Manganese accumulation in bone following chronic exposure in rats: Steady-state concentration and half-life in bone, Toxicology Letters. 2014; 229(1):93–100. Crossref. PMid: 24930841 PMCid:PMC4126163.

  • World Health Organization. Guidelines for drinking-water quality. 4th Edition. WHO Press: Switzerland; 2011. p. 1−24.

  • Indonesia Health Department. Regulation of Indonesia Health Minister number 416/MENKES/PER/IX/1990. Indonesia Health Department, Jakarta; 1990.

  • Kohl PPM, Medlar SJS. Occurrence of manganese in drinking water and manganese control. American Water Works Association: USA; 2006; p. 1−464. PMid: 16040083.

  • Delfino JJ, Lee GF. Chemistry of Manganese in Lake Mendota, Wisconsin, Environmental Science and Technology. 1968; 2(12):1094–100. Crossref.

  • Bidlack WR. Casarett and Doull’s Toxicology: The Basic Science of Poisons. 8th Edition. Mc Graw Hill Education/ Exclusively Distd.; 2013. p. 1−1454.

  • Guo Z, Zhang Z, Wang Q, Zhang J, Wang L, Zhang Q, Li H, Wu S. Manganese chloride induces histone acetylation changes in neuronal cells: Its role in manganese-induced damage, Neurotoxicology. 2018 March; 65:255−63. Crossref. PMid:29155171.

  • Ge X, Wang F, Zhong Y, Lv Y, Jiang C, Zhou Y, Li D, Xia B, Su C, Cheng H, Ma Y, Xiong F, Shen Y, Zou Y, Yang X. Manganese in blood cells as an exposure biomarker in manganese-exposed workers healthy cohort, Journal of Trace Elements in Medicine and Biology. 2018; 45:41−7. Crossref. PMid:29173481.

  • BrbootI MM, AbiD BA, Al-Shuwaki NM. Removal of heavy metals using chemicals precipitation, Engineering and Technology Journal. 2011; 29(3):595–612.

  • Gaikwad RW, Sapkal VS, Sapkal RS. Ion exchange system design for removal of heavy metals from acid mine drainage wastewater, Acta Montanistica Slovaca. 2010; 15(4):298–304.

  • Mihaly M, Comanescu AF, Rogozea EA, Meghea A. Nonionic microemulsion extraction of Ni (II) from waste-water, Molecular Crystals and Liquid Crystals. 2010; 523(1):63–72. Crossref.

  • Kozlowski CA, Walkowiak W. Removal of chromium (VI) from aqueous solutions by polymer inclusion membranes, Water Research. 2002; 36(19):4870–6. Crossref.

  • Shaalan HF, Sorour MH, Tewfik SR. Simulation and optimization of a membrane system for chromium recovery from tanning wastes, Desalination. 2001; 141(3):315–24. Crossref.

  • Maximous NN, Nakhla GF, Wan WK. Removal of Heavy Metals from Wastewater by Adsorption and Membrane Processes: a Comparative Study, International Journal of Environmental and Ecological Engineering. 2010; 4(4):594–9.

  • Shi J, Yi S, He H, Long C, Li A. Preparation of nanoscale zero-valent iron supported on chelating resin with nitrogen donor atoms for simultaneous reduction of Pb2+and NO3-, Chemical Engineering Journal. 2013; 230:166–71. Crossref.

  • Liguori F, Moreno-Marrodan C, Barbaro P. Metal nanoparticles immobilized on ion-exchange resins: A versatile and effective catalyst platform for sustainable chemistry, Chinese Journal of Catalysis. 2015; 36:1157–69. Crossref.

  • Hackbarth FV, Girardi F, de Souza SMAGU, de Souza AÔAU, Boaventura RAR, Vilar VJP. Marine macroalgae Pelvetia canaliculata (Phaeophyceae) as a natural cation exchanger for cadmium and lead ions separation in aqueous solutions, Chemical Engineering Journal. 2013; 242:294–305. Crossref.

  • Cechinel MAP, Mayer DA, Pozdniakova TA, Mazur LP, Boaventura RAR, de Souza AAU, de Souza SMAGU, Vilar VJP. Removal of metal ions from a petrochemical wastewater using brown macro-algae as natural cation-exchangers, Chemical Engineering Journal. 2016; 286:1–15. Crossref.

  • Bulgariu D, Bulgariu L. Sorption of Pb (II) onto a mixture of algae waste biomass and anion exchanger resin in a packedbed column, Bioresources Technology. 2013; 129:374–80. Crossref. PMid: 23262014.

  • Al-Wakeel KZ, Abd El Monem H, Khalil MMH. Removal of divalent manganese from aqueous solution using glycine modified chitosan resin, Journal Environmental Chemical Engineering. 2015; 3(1):179–86. Crossref.

  • Demirbas A, Pehlivan E, Gode F, Altun T, Arslan G. Adsorption of Cu(II), Zn(II), Ni(II), Pb(II), and Cd(II) from aqueous solution on Amberlite IR-120 synthetic resin, Journal Colloid Interface Science. 2005; 282(1):20–5. Crossref. PMid: 15576076.

  • Hallajiqomi M, Eisazadeh H. Adsorption of manganese ion using polyaniline and it’s nanocomposite: Kinetics and isotherm studies, Journal of Industrial and Engineering Chemistry. 2017; 55:191–7. Crossref.

  • Wang X, Guo Y, Yang L, Han M, Zhao J, Cheng X. Nanomaterials as Sorbents to Remove Heavy Metal Ions in Waste Water Treatment, Environmental and Analytical Toxicology. 2012; 2:2−7. Crossref.


Abstract Views: 128

PDF Views: 0




  • Removal of Manganese from Well-Water on Pasuruan, East Java, Indonesia using Fixed Bed Cation Exchanger and Prediction of Kinetics Adsorption

Abstract Views: 128  |  PDF Views: 0

Authors

Esthi Kusdarini
Mining Engineering Department, Adhi Tama Surabaya Institute of Technology, Surabaya, Indonesia
Agus Budianto
Chemical Engineering Department, Adhi Tama Surabaya Institute of Technology, Surabaya, Indonesia

Abstract


Objectives: Testing of a cation exchanger based water treatment apparatus and an Amberlite IR 120 Na resin medium to reduce the manganese content in the well-water is proposed. Methods/Statistical Analysis: Testing was done by wellwater treatment in a fixed bed cation exchanger in continuous flow. The variables used were the resin mass and flow rate and its effect on the manganese concentration in the outflow of the equipment. Manganese content was analyzed by Atomic Absorption Spectrophotometry (AAS) method. The isothermal adsorption equation was tested by the Freundich and Langmuir equations. Findings: The result of this research showed Amberlite resin IR 120 Na adsorbed manganese ion was about 96.3-98.9%; the optimal resin mass about 20 grams with a flow rate about 0.04 L.s-1 when viewed from an economic point. Resin absorption power to manganese increases with decreasing flow rate and increasing resin mass. Freundlich equation with constant n = 0.6539 and Kf = 4.6644 with correlation coefficient 0.7957. Langmuir equation with a constant As = -0.0927 and Kb = -6.3820 with a correlation coefficient -0.4314. Application/Improvements: Cation exchanger using Amberlite IR 120 Na resin media capable of remove manganese in well-water with efficiency > 96% and resin can be regenerated again.

References





DOI: https://doi.org/10.17485/ijst%2F2018%2Fv11i23%2F126372