Research Journal of Science and Technology

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Metal Catalyzed Oxidation of L-Arginine by Alkaline KMnO4:A Kinetic and Mechanistic Study


Affiliations
1 Utkal University, Vani Vihar, Bhubaneswer, Odisha, India
2 Govt Girls Polytechnic, Byron Bazar, Raipur C.G., India
     

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Metal catalysed oxidation of Arginine by Potassium permangate in highly basic medium were studied spectrophotometrically over the range 20< t< 30° C, I= 0.5,2x10-4 < oxidant 9x10-4 mol/dm3, 1x10-7 < catalyst< 5x10-7 mol/dm3. The reaction is 1st order with respect to the oxidant, substrate and catalyst. The activation parameters were calculated and tabulated.

Keywords

KMnO4, Arginine, Ruthenium Catalyst.
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  • Metal Catalyzed Oxidation of L-Arginine by Alkaline KMnO4:A Kinetic and Mechanistic Study

Abstract Views: 157  |  PDF Views: 0

Authors

Sandhyarani Panda
Utkal University, Vani Vihar, Bhubaneswer, Odisha, India
M. Satpathy
Govt Girls Polytechnic, Byron Bazar, Raipur C.G., India
P. Mohanty
Utkal University, Vani Vihar, Bhubaneswer, Odisha, India

Abstract


Metal catalysed oxidation of Arginine by Potassium permangate in highly basic medium were studied spectrophotometrically over the range 20< t< 30° C, I= 0.5,2x10-4 < oxidant 9x10-4 mol/dm3, 1x10-7 < catalyst< 5x10-7 mol/dm3. The reaction is 1st order with respect to the oxidant, substrate and catalyst. The activation parameters were calculated and tabulated.

Keywords


KMnO4, Arginine, Ruthenium Catalyst.