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Colloid Chemical and Antimicrobial Properties of some Quaternary Ammonium Compounds


Affiliations
1 Department of Physical Chemistry, Yerevan State University, Yerevan-375 049, A. Manoogian St. 1, Armenia
     

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A few chlorine substituted unsaturated quaternary ammonium compounds (QAC's) with varying alkyl chain lengths (n = 5 to 12) have been synthesized and found to behave as surfactants. Kraft points have been determined and the dependence of CMC, the degree of micellar aggregation and solubilisation ability on the alkyl chain length studied. Influence of additives, salts and alcohols, on colloid chemical behaviour has been presented. Role of the QAC's as emulisifiers has been explored with regard to styrene polymerisation kinetics. These compounds have been found to possess antimicrobial activity.

Keywords

Quaternary Ammonium Compounds, Micelle Formation, Emulsion Polymerization, Solubilization Kinetics, Antimicrobial Properties.
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  • Colloid Chemical and Antimicrobial Properties of some Quaternary Ammonium Compounds

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Authors

R. Haroutyunian
Department of Physical Chemistry, Yerevan State University, Yerevan-375 049, A. Manoogian St. 1, Armenia
A. Babakhanian
Department of Physical Chemistry, Yerevan State University, Yerevan-375 049, A. Manoogian St. 1, Armenia
N. Beylerian
Department of Physical Chemistry, Yerevan State University, Yerevan-375 049, A. Manoogian St. 1, Armenia

Abstract


A few chlorine substituted unsaturated quaternary ammonium compounds (QAC's) with varying alkyl chain lengths (n = 5 to 12) have been synthesized and found to behave as surfactants. Kraft points have been determined and the dependence of CMC, the degree of micellar aggregation and solubilisation ability on the alkyl chain length studied. Influence of additives, salts and alcohols, on colloid chemical behaviour has been presented. Role of the QAC's as emulisifiers has been explored with regard to styrene polymerisation kinetics. These compounds have been found to possess antimicrobial activity.

Keywords


Quaternary Ammonium Compounds, Micelle Formation, Emulsion Polymerization, Solubilization Kinetics, Antimicrobial Properties.