Current Science

Open Access Open Access  Restricted Access Subscription Access

Geochemical Pathways of Fluoride and Boron in the Alluvialaquifer of the Dwarka River Basin, India


Affiliations
1 Geo-Meteorological Risks Management Division, National Institute of Disaster Management, Ministry of Home Affairs, New Delhi 110 001, India
2 Department of Environmental Science, The University of Burdwan, Burdwan 713 104, India
 

Dwarka river basin, situated in the Birbhum district of West Bengal, India is endemic to fluorosis as groundwater contains fluoride as high as 14 mg/L (permissible limit 1.5 mg/L). Co-existence of boron (B) and fluoride (F–1 ) in groundwater, sometimes acts as a tool to predict the source of fluoride. This research was carried out with an objective to identify the geochemical relationship of these two elements and to find out their source(s) in groundwater. pH of groundwater of the study area was mostly neutral to alkaline, F– generally ranged from 0.1 to 10.6 mg/L and boron ranged from 0.01 to 0.5 mg/L. Fluoride and boron showed a strong positive correlation indicating similar source. Fluorapatite observed in sediment samples was considered to be the main source of fluoride. Clay minerals found in the sediment sample were considered to be the most probable source of boron.

Keywords

Birbhum, Boron, Fluoride, Fluoroapatite, Groundwater, Zeolite.
User
Notifications
Font Size

  • Deshmukh, A. N., Shah, K. C. and Sriram, A., Coal ash: a source of fluoride pollution, a case study of Koradi Thermal Power Station, District Nagpur, Maharashtra. Gondwana Geol. Mag.,1995, 9, 21–29.

  • Rao, S., Fluoride in groundwater, Varaha River Basin, Visakhapatnam District, Andhra Pradesh, India. Environ. Monit. Assess., 2009, 152, 47–60.

  • Karro, E., Indermitte, E., Saava, A., Haamer, K. and Marandi, A., Fluoride occurrence in publicly supplied drinking water in Estonia. Environ. Geol., 2006, 50, 389–396.

  • Smedley, P. L. and Kinniburgh, D. G., A review of the source, behaviour and distribution of arsenic in natural waters. Appl. Geo-chem., 2002, 17(5), 517–568; https://doi.org/10.1016/S0883-2927(02)00018-5.

  • PHED, Public Health Engineering Department, Government of West Bengal – activities and achievements in rural drinking water supply and other areas. 2007; http://www.wbphed.gov.in/applications/im/uploads/000643.pdf(accessed on 12 August 2018).

  • Thapa, R., Gupta, S. and Reddy, D. V., Application of geospatial modeling technique in delineation of fluoride contamination zones within Dwarka Basin, Birbhum, India. Geosci. Front., 2017, 8(5), 1105–1114; https://doi.org/10.1016/j.gsf.2016.11.006.

  • Edmunds, W. M. and Smedley, P. L., Fluoride in natural waters. In Essentials of Medical Geology(ed. Selinus, O.), Elsevier Academic Press, London, 2005, pp. 301–329.

  • Thapa, R., Gupta, S. and Kaur, H., Delineation of potential fluoride contamination zones in Birbhum, West Bengal, India, using remote sensing and GIS techniques. Arab. J. Geosci., 2017, 10(527), 1–18; https://doi.org/10.1007/s1251 7-017-3328-y.

  • Woods, W. G., An introduction to boron: history, sources, uses, and chemistry. Environ. Health Perspect., 1994, 102, 5–11.

  • Sen, K. K., Datta, R. K. and Bandopadhaya, S. K., Birbhum coal-field – a major coalfield discovered. Proceedings in National Level Seminar on Coal Resources of India, 1987, pp. 417–427.

  • Sen, K. K. and Vijaya, Palynological study of the Dubrajpur For-mation in the Mesozoic Succession, Pachami area, Birbhum coal-field, West Bengal. J. Palaeontol. Soc. Ind., 2005, 50(1), 121–133; http://palaeontologicalsociety.in/vol50_1/v8.pdf

  • Deng, Y., Nordstrom, D. K. and McCleskey, R. B., Fluoride geo-chemistry of thermal waters in Yellowstone National Park: I. Aqueous fluoride speciation. Geochim. Cosmochim. Acta, 2011, 75(2011), 4476–4489; https://doi.org/10.1016/j.gca.2011.05.028.

  • Thapa, R., Gupta, S., Gupta, A., Reddy, D. V. and Kaur, H., Geo-chemical and geostatistical appraisal of fluoride contamination: An insight into the Quaternary aquifer. Sci. Total Environ., 2018, 640–641, 406–418; https://doi.org/10.1016/j.scitotenv.2018.05.360.

  • Uppin, M. and Karro, E., Geologicalsources of boron and fluoride anomalies in Silurian–Ordovician aquifer system, Estonia. Environ. Earth Sci., 2012, 65, 1147–1156, doi: 10.1007/s12665-011-1363-7.

  • Desbarats, A. J., On elevated fluoride and boron concentrations in groundwaters associated with the Lake Saint-Martin impact structure, Manitoba. Appl. Geochem., 2009, 24(2009), 915–92.7; doi:10.1016/j.apgeochem.2009.02.016.

  • Pennisi, M., Bianchini, G., Muti, A., Kloppmann, W. and Gonfiantini, R., Behaviour of boron and strontium isotopes in ground-water–aquifer interactions in Cornia Plain (Tuscany, Italy). Appl. Geochem., 2006, 21, 1169–1183.

  • Rafique, T., Naseem, S., Bhanger, M. I. and Usmani, T. H., Fluoride ion contamination in the groundwater of Mithi sub-district, the Thar Desert, Pakistan. Environ. Geol., 2008, 56(2), 317–326; doi:10.1007/s00254-007-1167-y.

  • Appelo, C. A. J. and Postma, D., Geochemistry, Groundwater and Pollution, CRC Press, New York, 2005, 2nd edn.


Abstract Views: 168

PDF Views: 71




  • Geochemical Pathways of Fluoride and Boron in the Alluvialaquifer of the Dwarka River Basin, India

Abstract Views: 168  |  PDF Views: 71

Authors

Raju Thapa
Geo-Meteorological Risks Management Division, National Institute of Disaster Management, Ministry of Home Affairs, New Delhi 110 001, India
Srimanta Gupta
Department of Environmental Science, The University of Burdwan, Burdwan 713 104, India
Harjeet Kaur
Geo-Meteorological Risks Management Division, National Institute of Disaster Management, Ministry of Home Affairs, New Delhi 110 001, India

Abstract


Dwarka river basin, situated in the Birbhum district of West Bengal, India is endemic to fluorosis as groundwater contains fluoride as high as 14 mg/L (permissible limit 1.5 mg/L). Co-existence of boron (B) and fluoride (F–1 ) in groundwater, sometimes acts as a tool to predict the source of fluoride. This research was carried out with an objective to identify the geochemical relationship of these two elements and to find out their source(s) in groundwater. pH of groundwater of the study area was mostly neutral to alkaline, F– generally ranged from 0.1 to 10.6 mg/L and boron ranged from 0.01 to 0.5 mg/L. Fluoride and boron showed a strong positive correlation indicating similar source. Fluorapatite observed in sediment samples was considered to be the main source of fluoride. Clay minerals found in the sediment sample were considered to be the most probable source of boron.

Keywords


Birbhum, Boron, Fluoride, Fluoroapatite, Groundwater, Zeolite.

References





DOI: https://doi.org/10.18520/cs%2Fv118%2Fi8%2F1292-1296