Asian Journal of Research in Chemistry

Open Access Open Access  Restricted Access Subscription Access
Open Access Open Access Open Access  Restricted Access Restricted Access Subscription Access

Removal of phenolic compounds from aqueous solutions by petiole palm as a biosorbent


Affiliations
1 Chemical Department, Collage of Science, Baghdad University, Iraq
     

   Subscribe/Renew Journal


The aim of this work is to determine the potential of application of palm petiole as a biosorbent for removing of three phenolic compounds[phenol,2-chloro phenol(2-Cph) and 4- chloro phenol(4-Cph)] from aqueous solutions. The effect of pH, adsorbent dosage and contact time were investigated. Increase in the pH to neutrality resulted in the increase in the phenolic compounds adsorption capacity. The results showed that the increase in the petiole palm dosage to 0.5g/0.1L significantly increased the phenolic compounds adsorption rates. The adsorption process was fast, and it reached equilibrium in 30 min. contact time. The Freundlich and Langmuir adsorption models were used for mathematical description of the adsorption equilibrium and it was found that experimental data fitted very well to both Freundlich and Langmuir models. These results indicate clearly the efficiency of petiole as a low-cost solution for these compounds in aqueous solutions treatment and give some preliminary elements for the comprehension of the interactions between palm petiole as a bioadsorbent and the very polluting compounds from aqueous solutions.
Subscription Login to verify subscription
User
Notifications
Font Size


  • M. Khalid, G. Joly, A. Renaud, P. Magnoux, Ind. Eng. Chem. Res. 43, 5275, (2004)

  • G. Bayramoglu, M. Y. Arica, J. Hazard. Mater. 156, 148, (2008)

  • Tepe, O.; Dursun, A. Y. J. Hazard. Mater. 151, 9, (2008) 4. F. A. Banat, V. Al-Bashir, S. Al-Asheh, O. Hayajneh, Environ. Pollut. 107, 391, (2000)

  • A. Knop, L. A. Pilato, Phenolic Resins—Chemistry, Applications and Performance, Springer-Verlag, 1985.

  • WHO (World Health Organization), Guidelines for Drinking Water Quality (vol. II): Health Criteria and Supporting Information, World Health Organization, Geneva, Switzerland, 1984.

  • N. N. Dutta, S. Brothakur, R. Baruaha, Water. Environ. Res. 70, 4, (1998)

  • J. S. Ra, S.-Y. Oh, B. C. Lee, S. D. Kim, Environ. Inter. 34, 184, (2008)

  • A. H. Mollah, C. W. Robinson, Water Res. 30, 2901, (1996)

  • A. R. Khan, T. A. Al-Bahri, A. Al-Haddad, Water Res. 31, 2102 (1997)

  • D. Batabyal, A. Sahu, S. K. Chaudhuri, Sep Sci Technol. 5, 179 (1995)

  • E. Mona, R. Zein, R. Kurniadi, I. Kurniadi, Environ. Technol. 18, 355, (1997)

  • T. Viraraghavan, F. De Maria Alfaro, J. Hazard. Mater. 57, 59, (1998)

  • S. Hasan Basri, O. Duygu, G. Ali, D. Celal, S. Mustafa, J. Hazard. Mater. 172, 353, (2009)

  • A. M. Li, Q. X. Zhang, G. C. Zhang, J. L. Chen, Z. H. Fei, F. Q. Liu, Chemosphere. 47, 981, (2002)

  • B. C. Pan, X. Zhang, W. M. Zhang, J. Z. Zheng, B. J. Pan, J. L. Chen, Q. X. Zhang, J. Hazard. Mater. 121, 233, (2005)

  • V. K. Garg, R. Gupta, A. Bala, R. Kumar, Bioresour. Technol. 89, 121, (2009)

  • M. A. Abdulkarim, N. A. Darwish, Y. M. Magdy, A. Dwaidar, Eng. Life Sci. 2, 161, (2002)

  • J. R. Rao, T. Viraraghavan, Bioresour. Technol. 85, 165, (2002)

  • R. Chakravarty, D. C. Rupainwar, Environ. Technol. 20, 397, (1999)

  • G. Vazquez, J. Gonzalez-Alvarez, S. Freire, M. Lopez-Lorenzo, G. Antorrena, Bioresour. Technol. 82, 247, (2002)

  • I. P. Bras, L. Santos, A. Alves, Environ. Sci. Technol. 33, 631, (1999)

  • G. Vazquez, J. Gonzalez-Alvarez, A. I. Garcia, M. S. Freire, G. Antorrena, Bioresour. Technol. 98, 1535, (2007)

  • A. Latef and H.Faris,Chem.J.22,55(1988)

  • D. Fooad and S.Saad,Environ.Sci.Iraq.J.2,43,(2006)

  • G. Ghader, A, Ahmed, S, Areej, Environ.Sci.Iraq.J.6,47,(2008)

  • E. Raad, N. Naman, S. Hadi, V. Ghath, Agriculture J.Iraqi.5, 37, (2009)

  • S. Sahaer, D. Khdem ,K. Khailed, Environ.Sci.Iraq.J.2, 105, (2006)

  • L. Mandi1, M. Achak, A. Hafidi, N. Ouazzani, Environ. Technol. 20, 409, (1999)

  • A. Latef, H. Faris, F. Khailed ,Chem.J.88,12(1990)

  • Chan L.S., Cheung W.H. and McKay G., Desalination, 218:304– 312, (2008)

  • Lata H., Grag V.K. and Gupta R.K., Desalination, 219:250– 261.(2008)

  • HO Y.S., Huang C.T. and Huang H.W, Process Biochem. 37:1421-1430.( 2002)

  • Mohd Din A. T., Hameed B.H. and Ahmad A.L., J. Hazard. Mater. Doi:10.1016/j.jhazmat. 05.009. (2008)

  • Annadurai G., Juang R. S. and Lee D. J., J. Hazard. Mater. 92:263-274. (2002)

  • N. Siva Kumar, M. Venkata Subbaiah, A. Subba Reddy, A. Krishnaiah, J. Chem. Technol. Biotechnol. 84, 972, (2009)

  • V. C. Srivastava, M. M. Swamy, I. D. Mall, B. Prasad, I. M. Mishra, Colloids Surf. A: Physicochem. Eng. Aspects. 272, 89, (2006)

  • K. M. Parida, A. C. Pradhan, J. Hazard. Mater. 173, 758, (2010)

  • E. Rubin, P. Rodriguez, R. Herrero, M. Sastre de Vicente, J. Chem. Technol. Biotechnol. 81, 1093, (2006)

  • N. KUMAR and K. Min J. Chil. Chem. Soc., 56: 539-545(2011)

  • B. K. Singh, N. S. Rawat, J. Chem. Technol. Biotechnol. 16, 307, (1994)

  • N. Siva Kumar, S. Kalyani, V. M. Boddu, A. Krishnaiah, J. Hazard. Mater. 162, 482, (2008)

  • V. C. Srivastava, M. M. Swamy, I. D. Mall, B. Prasad, I. M. Mishra, Colloids Surf. A: Physicochem. Eng. Aspects. 272, 89, (2006)

  • M. Otero, F. Rozada, L. F. Calvo, A. I. Garca, A. Moran, Dyes. Pigm. 57, 55, (2003)

  • B. Ozkaya, J. Hazard. Mater. 129, 158, (2006)


Abstract Views: 235

PDF Views: 5




  • Removal of phenolic compounds from aqueous solutions by petiole palm as a biosorbent

Abstract Views: 235  |  PDF Views: 5

Authors

Bushra B. Qassim
Chemical Department, Collage of Science, Baghdad University, Iraq

Abstract


The aim of this work is to determine the potential of application of palm petiole as a biosorbent for removing of three phenolic compounds[phenol,2-chloro phenol(2-Cph) and 4- chloro phenol(4-Cph)] from aqueous solutions. The effect of pH, adsorbent dosage and contact time were investigated. Increase in the pH to neutrality resulted in the increase in the phenolic compounds adsorption capacity. The results showed that the increase in the petiole palm dosage to 0.5g/0.1L significantly increased the phenolic compounds adsorption rates. The adsorption process was fast, and it reached equilibrium in 30 min. contact time. The Freundlich and Langmuir adsorption models were used for mathematical description of the adsorption equilibrium and it was found that experimental data fitted very well to both Freundlich and Langmuir models. These results indicate clearly the efficiency of petiole as a low-cost solution for these compounds in aqueous solutions treatment and give some preliminary elements for the comprehension of the interactions between palm petiole as a bioadsorbent and the very polluting compounds from aqueous solutions.

References