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Inhibition of Corrosion of Copper by 4-Amino-3-Phenyl-5-Mercapto-1, 2, 4-Triazole in 3.5% Sodium Chloride Solution


Affiliations
1 Department of Applied Chemistry, ISM University, Dhanbad, India
2 Department of Chemistry, S.N. PG College, Azamgarh, India
     

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In the present investigation 4-amino-3-phenyl-5-mercapto-1, 2, 4-triazole has been synthesized and studied as inhibitor for the corrosion of copper in 3.5 % NaCl solution. The inhibition efficiency of the compound have been evaluated by weight loss and electrochemical methods (Impedance spectroscopy and polarization curves). The surface study was done by using SEM techniques. The inhibitor appears to inhibit corrosion process through formation of protective film which was found to consist of Cu(I)-inhibitor complex, cuprous chloride, CuCl or CuCl2- complex ion or both on the surface.

Keywords

Copper, Corrosion Inhibition, 3.5% NaCl Solution.
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  • Inhibition of Corrosion of Copper by 4-Amino-3-Phenyl-5-Mercapto-1, 2, 4-Triazole in 3.5% Sodium Chloride Solution

Abstract Views: 192  |  PDF Views: 1

Authors

M. Yadav
Department of Applied Chemistry, ISM University, Dhanbad, India
Sushil Kumar
Department of Applied Chemistry, ISM University, Dhanbad, India
Abu Nasar
Department of Chemistry, S.N. PG College, Azamgarh, India
Sunil Kumar
Department of Chemistry, S.N. PG College, Azamgarh, India

Abstract


In the present investigation 4-amino-3-phenyl-5-mercapto-1, 2, 4-triazole has been synthesized and studied as inhibitor for the corrosion of copper in 3.5 % NaCl solution. The inhibition efficiency of the compound have been evaluated by weight loss and electrochemical methods (Impedance spectroscopy and polarization curves). The surface study was done by using SEM techniques. The inhibitor appears to inhibit corrosion process through formation of protective film which was found to consist of Cu(I)-inhibitor complex, cuprous chloride, CuCl or CuCl2- complex ion or both on the surface.

Keywords


Copper, Corrosion Inhibition, 3.5% NaCl Solution.