Refine your search
Collections
Co-Authors
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z All
Dayalan, A.
- Aquatic Toxicity of Dimethyl Sulphoxide on the Indian Major Carp, Catla catla (Hamilton)
Abstract Views :389 |
PDF Views:88
Authors
Affiliations
1 Department of Zoology, Sir Thyagaraya College, Chennai-600 021, IN
2 Department of Chemistry, Loyola College, Chennai-600 034, IN
1 Department of Zoology, Sir Thyagaraya College, Chennai-600 021, IN
2 Department of Chemistry, Loyola College, Chennai-600 034, IN
Source
Indian Journal of Science and Technology, Vol 1, No 4 (2008), Pagination: 1-4Abstract
DMSO is frequently used as carrier solvent in toxicological experiments due to its exceptionally low toxicity and environmental impact and also to achieve more effective dispersion of the toxicants. Aquatic toxicity studies of DMSO on the respiratory rates and the biochemical constituents of muscle and liver in catla revealed minimal lethality and negligible effect on the physiology of the test organism. This study helps in the choice of percentage of the carrier solvent that can be used in the preparation of toxicants for any toxicological studies involving fish.Keywords
Aquatic Toxicity, Dimethyl Sulphoxide, Catla catlaReferences
- Anon (1984) Water quality management in aquaculture, (CMFRI Special publication No.22). CMFRI, Cochin.
- Bhttacharya S (2001) Stress response to pesticides and heavy metals in fish and other vertebrates. Proc Indian Nat Acad (Part B). 673, 215-246.
- Carrol WV, Longley RW and Roe JH (1956) The determination of glycogen in the liver and muscle by the use of Anthrone reagent. J Biol Chem. 220, 583-593.
- Dhanapakiam P and Ramasamy VK (2001) Toxic effects of copper and zinc mixtures on some haematological and biochemical parameters in common carp, Cyprinus carpio (Linn.). J Environ Biol. 22, 105-116.
- Hutchinson TH, Shillabeer N, Winter MJ and Pickford DB (2006) Acute and chronic effects of carrier solvents in aquatic organisms:A critical review. Aquatic Toxicology. 76, 69-92.
- Jayaraman J (1988) (Bligh and Dyer method), in Laboratory Manual in Biochemistry (Willey Eastern Ltd). New Delhi, 96.
- Johannesson H, Denisov VP and Halle B (1997) Dimethyl sulfoxide binding to globular proteins: A nuclear magnetic relaxation dispersion study. Protein Sci. 6, 1756-1763.
- Kumar S and Singh M (2000) Toxiciy of dimethoate to a freshwater teleost, Catla catla (Ham.). J .Exp. Biol. 3, 83-88.
- Lowry OH, Rosebrough NJ, Farr AL and Randall RJ (1951) Protein measurement with folin phenol reagent. J. Biol. Chem. 193, 265- 275.
- Mathivanan R (2004) Effects of sublethal concentration of quinalphos on selected respiratory and biochemical parameters in the freshwater fish, Oreochromis mossambicus. J. Ecotoxicol. Environ. Moni. 14, 57-64.
- Meha B, Vankhede GN and Dhande RR (2004) Heavy metal induced Biochemical alterations in the freshwater fish Labeo rohita. J Ecotoxicol Environ Moni. 14, 1-7.
- Mortensen AS and Arukwe A (2006) Dimethyl sulfoxide is a potent modulator of estrogen receptor isoforms and xenoestrogen biomarker responses in primary culture of salmon hepatocytes. Aquatic Toxicology. 79, 99-103.
- Nanda PL, Nath DP and Behera KM (2002) Respiratory metabolism of fish Oreochromis mossambicus (Peters) exposed to pulp and paper mill effluents. Env. Eco. 20, 570-572.
- Omprakasam M and Manohar L (1991) Experimental infection of some bacterial fish pathogens in the cichlid fish, Oreochromis mossambicus. Indian J Fish. 38, 106-110.
- Santhakumar M and Balaji M (2000) Acute toxicity of an organophosphorus insecticide monocrotophos and its effects on behaviour of an air breathing fish Anabas testudineus (Bloch). J. Environ. Biol. 21, 121-123.
- Shrivastava S and Singh S (2004) Changes in protein content in the muscle of Hetropneustes fossilis exposed to carbaryl. J. Ecotoxicol. Environ. Monit.14, 119-122.
- Sujatha LB (2006) Studies on the physiology, haematology and histopathology in the Indian Major Carp, Catla catla (Hamilton), as influenced by individual and synergistic toxic effects of a pesticide and two metallic compounds. Ph.D. thesis, University of Madras.
- Tilak KS, Satyavardhan K and Thathaji PB (2003) Biochemical changes induced by fenvalerate in the freshwater fish Channa punctatus. J. Ecotoxicol. Environ. Monit. 13,261-270.
- Willford WA (1967) Toxicity of dimethyl sulfoxide to fish, in Investigations in fish control (Resource publication) United States Bureau of Sport Fisheries and Wildlife. No.37 8p.
- Yang R, Brauner C, Thurston V, Neuman J and Randall DJ (2000) Relationship between toxicant transfer kinetic processes and fish oxygen consumption. Aqua. Toxicol. 48, 95- 108.
- Synthesis and Characterization of Halocobaloximes and its Derivatives for Antimicrobial Activity
Abstract Views :336 |
PDF Views:127
Authors
S. Martin
1,
A. Dayalan
1
Affiliations
1 Department of Chemistry, Loyola College (Autonomous), Chennai-600 034, IN
1 Department of Chemistry, Loyola College (Autonomous), Chennai-600 034, IN
Source
Indian Journal of Science and Technology, Vol 2, No 9 (2009), Pagination: 59-62Abstract
Cobaloximes of the types Trans- BH2[Co(dmgH)2X], where dmgH- = Dimethylglyoximate, X- = Cl- or Br- and Trans-[Co(dmgH)2(H2O)I].B where, B = Piperazine (Pp) or 2-(N-Tert-butylamido)piperazine (t- Bu-PpAM) were prepared and characterized by TG/DTA, FABMS UV-visible, IR, NMR spectra and XRD studies. All the cobaloximes were screened against microorganisms for their antimicrobial activity and compared with streptomycin as standard. The free ligands viz., Pp&t- Bu-PpAM, showed antimicrobial activity in the order: Pp < t-Bu-PpAM. Most of the cobaloximes were found to be more active than the corresponding ligands such that the antimicrobial activity order for the axial halides was found to be Cl- > Br- > I - for cobaloximes having piperazine where as in the case of cobaloximes having 2-(N-Tertbutylamido) piperazine the antimicrobial activity order was found to be reversed as Br - > Cl- >I- .Keywords
Cobalt(III) Complexes, Cobaloximes, Antimicrobial Activity of Cobalt (III) ComplexesReferences
- Acheson RM (1967) Introduction to the chemistry of hetero cyclic compounds. 2nd edn, Wiley Eastern Ltd. pp: 346-347.
- Brown TM, Dronsfield AT and Wilkinson AS (1997) Thermochemical studies of benzyl cobaloximes: a decomposition pathway different from that reported for the alkyl analogues. Inorg. Chem. Acta. 262, 97-101.
- Dayalan A and Vijayaraghavan VR (1993) Iron (II) reduction of halogenopyridinecarboxylatocobalt (III)-dioxime complexes: kinetics and mechanism. In: Proc. Indian Acad. Sci. (Chem.Sci.) 105 (2), 95-101.
- Dayalan A and Vijayaraghavan VR (2001) Chromium (II) reduction of cobalt(III) complexes of 3,8-dimethyl-5,6 benzo – 4,7-diazadeca-3,7-diene-2,9-dione dioxime: Kinetics and Mechanism. Indian J. Chem. 40A, 959.66, C.
- Dodson B, Glusker JP and Sayre D (1981) Structural studies on molecules of biological interest- A volume in honour of Dorothy Hodgkin. Clarendon, Oxford.
- Kitson KE (1950) simultaneous spectrophotometric determination of cobalt, copper and iron. Anal. Chem. 22, 664-667.
- Martin S, Revathi C, Dayalan A, Mathivanan N and Shanmugaiya V (2008) Halocobaloxime containing coordinated pyrazine, pyrazine carboxylic acid and pyrazine carboxamide:Microwave assisted synthesis, characterization and antibacterial activity. Rasayan J. Chem. 1, 378-389.
- Murray PR, Baron EJ, Pfaller MA, Tenover FC and Yolke RH (1995) Manual of clinical microbiology. Vol. 6. ASM, Washington, DC.
- Nayak SC, Das PK and Sahoo K (2003) The thermal and spectral properties of trans-[chloro-bis (dimethylglyoximato) Co(III)] complexes containing heterocyclic donor ligands. J. Anal. Appl. Pyrolysis. 70, 699-709.
- Pahor M, Forcolin P, Toscano J, Summers MF, Randaccio L and Marzilli LG (1985) Organocobalt B12 models: axial ligand effects on the structural and coordination chemistry of cobaloximes. Coord. Chem. Rev. 63, 1-125.
- Pratt JM (1972) Inorganic chemistry of Vitamin-B12. Academic Press, London, New York. pp: 193,284-285.
- Rai BK, Kumar K, Srivatsava YP (2005) Spectroscopic investigation and antifungal studies of some mixed ligand complexes of Co(II), Ni(II) and Cu(II) with 6-methyl-2-pyridyl formamide semicarbazone and thiosemicarbazone. Asian J.Chem. 17(3),1773-1779.
- Shamsipur M, Salimi A, Haddadzadeh H and Mousavi MF (2001) Electrocatalytic activity of cobaloxime complexes adsorbed on glassy carbon electrodes toward the reduction of dioxygen. J. Electroanal. Chem. 517, 37-44.
- Silverstein RM and Bassler GC (1984) Spectrometric identification of organic compounds. 2nd edn, John Wiley and sons, 458-465.
- Sllema B, Ramesh Babu MG (2005) Antibacterial studies of nickel (II) complexes of heterocyclic Schiff Bases. Asian J.Chem. 17 (3), 1473-1477.
- Vijayraghavan VR and Dayalan A (1992) Synthesis and characterisation of Trans-halogeno-pyridinecarboxamide bis (dimethylglyoximato) cobalt (III) complexes. J. Indian Chem. Soc. 69, 383-386.