Refine your search
Collections
Co-Authors
Year
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z All
Villabona-Ortiz, A.
- Removal of Cr (VI) from Aqueous Solution using Orange Peel-based Biosorbents
Abstract Views :181 |
PDF Views:0
Authors
Affiliations
1 Department of Chemical Engineering, University of Cartagena, Cartagena, Bolivar, CO
1 Department of Chemical Engineering, University of Cartagena, Cartagena, Bolivar, CO
Source
Indian Journal of Science and Technology, Vol 11, No 13 (2018), Pagination:Abstract
Background: Now-a-days, adsorption has been recognized as an effective method to remove heavy metals ions in water sources. Objectives: This work is focused on studying removal of chromium (VI) from aqueous solution by orange peel-based adsorbents (OP, OPAC, OP-CaCl2 and OP-Chitosan). Effects of pH and adsorbent dosage on the adsorption of Cr (VI) were evaluated in order to determine suitable conditions for carrying out adsorption process. Methods/ Analysis: OP-CaCl2 and OPAC biosorbents were obtained by chemical modification using CaCl2 and H3PO4 acid solution, respectively, while OP-Chitosan was synthetized in acetic acid solution. FT-IR analysis was performed to OP and OP-Chitosan materials. The pH of heavy metal ions solutions was adjusted to3, 4 and 5 and adsorbent dosage was varied in 2, 4 and 6 g/L. Batch experiments were carried out in a magnetic stirrer plate at 30°C using 100 ppm Cr (VI) ions solution. Experimental data of equilibrium were used to calculate adsorption isotherms. Findings: The adsorption of Cr (VI) was found to be maximum for OPAC biosorbent and its highest removal yield (66.8%) was achieved at pH 3 and dosage of 6 g/L. Application of the Langmuir isotherm to OP biosorbent yielded a maximum adsorption capacity of 911.21 mmol/g and the data for OPAC and OP-Chitosan obeyed Freundlich isotherm with KL of 0.25 mmol/g and 8.17 mg/g, respectively. The heterogeneity factor (1/n) indicated that OPAC obeys to cooperative adsorption and OP-Chitosan to chemisorption. Application/Improvement: Compared to the various other adsorbents reported in the literature, the orange peel-based adsorbents in this study show very good promise for practical applicability.Keywords
Adsorption, Biosorbent, Chromium, Heavy Metal, Removal- A Comparative Study of Cadmium, Nickel and Chromium Adsorption using Residual Biomass from Elaeisguineensis Modified with Al2o3 Nanoparticles
Abstract Views :207 |
PDF Views:0
Authors
A. Herrera-Barros
1,
C. Tejada-Tovar
1,
A. Villabona-Ortiz
1,
A. D. Gonzalez-Delgado
1,
J. Benitez-Monroy
1
Affiliations
1 Department of Chemical Engineering, University of Cartagena, Cartagena, Bolivar, CO
1 Department of Chemical Engineering, University of Cartagena, Cartagena, Bolivar, CO
Source
Indian Journal of Science and Technology, Vol 11, No 21 (2018), Pagination: 1-7Abstract
Background: The biosorption technology has been recognized as an attractive alternative for heavy metal ions uptake due to its several advantages as low cost and environmental friendly. Objectives: In this work, a biosorbent was synthesized from African oil palm bagasse biomass and alumina nanoparticles in order to use it for removing cadmium, nickel and chromium from aqueous solution. Methods/Analysis: The synthesis of Al2O3 was performed according to sol-gel methodology. The nanoparticles were loaded into biomass using an organic solvent. The resulting material was characterized by FT-IR, SEM and EDX analyses. The point of zero charges as well as ultimate analysis were also carried out for biomass. Findings: The FT-IR analysis revealed absorption bands characteristic of lignocellulosic biomass attributed to carboxyl, hydroxyl and amides functional groups. The presence of O-Al-O and Al-C=O suggested the successful synthesis of biosorbent. The morphology was identified as porous which enhances adsorption process. The EDX analysis confirms that carbon is the major constituent of biosorbent, similar to the results of ultimate analysis of African oil palm bagasse. In addition, removal yield values for cadmium, nickel and chromium of 92.02, 87.06 and 4%, respectively, were achieved at pH=6. Novelty/Improvement: This biosorbent exhibited excellent adsorption properties and could be used efficiently for removing cadmium and nickel water pollutants.References
- Wei D, Hao H, Guo W, Xu W, Du B, Saddam M. Biosorption performance evaluation of heavy metal onto aerobic granular sludge-derived biochar in the presence of effluent organic matter via batch and fluorescence approaches. Bioresource Technology. 2018; 249:410-6. Crossref. PMid:29059624.
- Ramrakhiani L, Halder A, Majumder A, Mandal AK, Majumdar S, Ghosh S. Industrial waste derived biosorbent for toxic metal remediation: Mechanism studies and spent biosorbent management. Chemical Engineering Journal. 2017; 308:1048-64. Crossref.
- Zang T, Cheng Z, Lu L. Removal of Cr(VI) by modified and immobilized Auricularia auricula spent substrate in a fixed-bed column. Ecological Engineering. 2017; 99:358-65. Crossref.
- Sahmoune MN. Performance of Streptomyces rimosus biomass in biosorption of heavy metals from aqueous solutions. Microchemical Journal. 2018.
- Rashid T, Gnanasundaram N, Appusamy A, Fai C. Enhanced lignin extraction from different species of oil palm biomass: Kinetics and optimization of extraction conditions. Industrial Crops & Products. 2018; 116:122-36. Crossref.
- PerezPK, Olivares BM, GonzalezMD, Gonzalez-Delgado AD. Exergy analysis of hydrogen production from palmoil solid wastes using indirect gasification. Indian Journal of Science and Technology. 2018; 11(2):1-6.
- Tejada-Tovar C, Gonzalez-Delgado AD, Villabona-Ortiz A. Removal of Cr (VI) from Aqueous Solution using Orange Peel-based Biosorbents. Indian Journal of Science and Technology. 2018; 11(13):1-13. Crossref. Crossref. Crossref. Crossref.
- Li Y, Cao L, Li L, Yang C. In situ growing directional spindle TiO2 nanocrystals on cellulose fibers for enhanced Pb2+ adsorption from water. Journal of Hazardous Materials. 2015; 289:140-8.
- Padmavathy K, Madhu G, Hassena P. A study on effects of pH, adsorbent dosage, time, initial concentration and adsorption isotherm study for the removal of hexavalent chromium (Cr (VI)) from wastewater by magnetite nanoparticles. Procedia Technology. 2016; 24:585-94.
- Pinzon-Bedoya M, Cardona-Tamayo A. Caracterizacion de la cascara de naranja para su uso como material bioadsorbente. Bistua. 2008; 6(1):1-23.
- Hossain M, Ngo H, Guo W, Nguyen T. Palm oil fruit shells as biosorbent for copper removal from water and wastewater: Experiments and sorption models. Bioreseource Technology. 2012; 113:97-101. Crossref.PMid:22204888.
- Li J, Pan Y, Xiang C, Ge Q, Guo J. Low temperature synthesis of ultrafine α-Al2O3 powder by a simple aqueous sol-gel process. Ceramics International. 2006; 32(5):58791. Crossref.
- Sadri M, Pedbeni A, Hossein H. Preparation of Biopolymeric Nanofiber Containing Silica and Antibiotic. Journal of Nanostructures. 2016; 6(1):96-100.
- Mohseni M, Gilani K, Mortazavi SA. Preparation and Characterization of Rifampin Loaded Mesoporous Silica Nanoparticles as a Potential System for Pulmonary Drug Delivery. Iranian Journal of Pharmaceutical Research. 2015; 14(1):27-34.
- Rodriguez J. Modificacion y Caracterizacion Calorimetrica de Carbon Activado Granular, para la Remocion de Cd (II) y Ni (II) en Adsorcion Simple y Competitiva. Universidad Nacional de Colombia Bogota, Colombia. 2011; p. 1-122.
- Alves V, Mosquetta R, Coelho N. Determination of cadmium in alcohol fuel using Moringa oleifera seeds as a biosorbent in an on-line system coupled to FAAS. Talanta. 2010; 80(3):1133-8. Crossref. PMid:20006064.
- Ngo H, Hossain M, Guo W, Nguyen T. Palm oil fruit shells as biosorbent for copper removal from water and wastewater: Experiments and sorption models. Bioresource Technology. 2012; 113:97-101.PMid:22204888.
- Skoog DA, Holler FJ, Nieman TA. Principios de analisis instrumental. Madrid McGraw-Hill. 2001; p. 122-50.
- Carmona S. Elaboracion y caracterizacion de peliculas delgadas de oxido de aluminio: propiedades opticas, estructurales y electricas. Instituto Politecnico Internacional Mexico DF. 2008; p. 1-112.
- Prado J, Montira S, Ghislandi M, Barros T, Schulte K. Surface Modification of Alumina Nanoparticles with Silane Coupling Agents. Sociedad Brasileira de Quimica. 2010; 21(12):2238-45.
- Goyal P, Srivastava S. Characterization of novel Zea Mays based biomaterial designed for toxic metals biosorption. Journal of Hazardous Materials. 2009; 172:1206-11.
- Oickle A, Goertzen S, Hopper K, Abdalla Y, Andreas H. Standardization of the Boehm titration: Part II. Method of agitation, effect of filtering and dilute titrant. Carbon. 2010; 48(12):3313-22. Crossref.
- Benitez M, Perez M, Pena P, J. P. Aluminas porosas: El metodo de bio-replica para la sintesis de aluminas estables de alta superficie especifica. Boletin de la Sociedad Espa-ola de Ceramica y Vidrio. 2013; 52(6):251-67. Crossref.
- Li J, Pan Y, Xiang C, Ge Q, Guo J. Low temperature synthesis of ultrafine α-Al2O3 powder by a simple aqueous sol-gel process. Ceramics International. 2006; 32(5):58791. Crossref.
- Banerjee S, Dubey S, Gautam RK, Chattopadhyaya MC, Sharma YC. Adsorption characteristics of alumina nanoparticles for the removal of hazardous dye, Orange G from aqueous solutions. Arabian Journal of Chemistry. 2017.
- Gupta A, Balomajumder C. Simultaneous removal of Cr(VI) and phenol from binary solution using Bacillus sp. immobilized onto tea waste biomass. Journal of Water Process Engineering. 2015; 6:1-10.
- Tejada-tovar C, Lopez-Cantillo K, Vidales-Hernandez K, Villabona-ortiz A, Acevedo-Correa D. Kinetics and Bioadsortion Equilibrium of Lead and Cadmium in Batch Systems with Cocoa Shell (Theobroma Cacao L.). Contemporary Engineering Sciences. 2018; 11(23):1111-20.
- Tejada-Tovar C, Herrera-Barros A, Villabona-Ortiz A, Gonzalez-Delgado A, Nu-ez-Zarur J. Hexavalent Chromium Adsorption from Aqueous Solution Using Orange Peel Modified with Calcium Chloride: Equilibrium and Kinetics Study. Indian Journal of Science and Technology. 2018; 11(17):1-10. Crossref.
- Tejada-Tovar C, Villabona-Ortiz A, Ruiz-Paternina E. Adsorcion de ni (ii) por cascaras de-ame (Dioscorearotundata) y bagazo de palma (Elaeisguineensis) pretratadas. Luna Azul. 2016; 42:30-43.
- Adsorption of Nickel And Cadmium by Corn Cob Biomass Chemically Modified with Alumina Nanoparticles
Abstract Views :181 |
PDF Views:0
Authors
A. Herrera-Barros
1,
C. Tejada-Tovar
2,
A. Villabona-Ortiz
2,
A. D. Gonzalez-Delgado
1,
J. Alvarez-Calderon
1
Affiliations
1 Department of Chemical Engineering, Nanomaterials and Computer Aided Process Engineering Research Group (NIPAC), University of Cartagena, Cartagena, Bolivar, CO
2 Department of Chemical Engineering, Process Design and Biomass Utilization Research Group (IDAB), University of Cartagena, Cartagena, Bolivar, CO
1 Department of Chemical Engineering, Nanomaterials and Computer Aided Process Engineering Research Group (NIPAC), University of Cartagena, Cartagena, Bolivar, CO
2 Department of Chemical Engineering, Process Design and Biomass Utilization Research Group (IDAB), University of Cartagena, Cartagena, Bolivar, CO
Source
Indian Journal of Science and Technology, Vol 11, No 22 (2018), Pagination: 1-11Abstract
Background: In recent decades, agricultural residues have been widely applied in the development of novel materials in order to obtain high-value products and reduce disposal issues. Objectives: In this work, corn cob residual biomass was used to prepare a biosorbent chemically modified with alumina nanoparticles. Methods/Analysis: The alumina nanoparticles were synthesized by sol-gel methodology and loaded into biomass matrix using an organic solvent. The corn cob biomass was characterized by ultimate analysis, FT-IR technique, Boehm titration and point of zero charges method, which provide information related charge of biomass surface, diversification of functional groups and elemental composition. SEM and EDX analyses were also performed in order to study morphology and composition of the prepared biosorbent. Batch adsorption experiments were carried out to evaluate the effect of pH and particle size on adsorption efficiency and determine suitable conditions for further experimentation. Findings: The physicochemical characterization of corn cob biomass revealed the presence of carboxyl, hydroxyl and amine functional groups in FT-IR spectrum. After loading alumina nanoparticles, this spectrum exhibited characteristic peaks of aluminum bonds suggesting a successful synthesis. In addition, it was observed that pH played an important role in removal yield results, hence, pH=6 were selected as suitable value for performing further experiments. The removal yield for cadmium and nickel ions using chemically modified biomass were 91 and 86%, respectively, results higher than those obtained using biomass. Novelty/Improvement: The modification with Al2O3 nanoparticles enhances adsorption process and could be applied to other sources of biomass.References
- Salakhum S, Yutthalekha T, Chareonpanich M, Limtraku J, Wattanakit C. Synthesis of hierarchical faujasite nanosheets from corn cob ash-derived nanosilica as efficient catalysts for hydrogenation of lignin-derived alkylphenols. Microporous and Mesoporous Materials. 2018; 258:141-50. Crossref.
- Mahmoud M. Kinetics studies of uranium sorption by powdered corn cob in batch and fixed bed system. Journal of Advanced Research. 2016; 7(1):79-87. Crossref. PMid:26843973 PMCid:PMC4703490.
- Kaur A, Sharma S. Removal of Heavy Metals from Waste Water by using Various Adsorbents-A Review. Indian Journal of Science and Technology. 2017; 10(34):1-14. Crossref.
- Tovar TC, Barros HA, Ortiz VA, Delgado GA, Zarur NJ. Hexavalent Chromium Adsorption from Aqueous Solution Using Orange Peel Modified with Calcium Chloride: Equilibrium and Kinetics Study. Indian Journal of Science and Technology. 2018; 11(17):1-10.Crossref.
- Cogollo CE, Ramos RY, Delgado OK. Evaluation of the Biogas Productivity Potential of Maize Waste Using Ruminal Fluid and Pig Manure. Contemporary Engineering Sciences. 2018; 11(7):307-15. Crossref.
- Padmavathy K, Madhu G, Hassena P. A study on effects of pH, adsorbent dosage, time, initial concentration and adsorption isotherm study for the removal of hexavalent chromium (Cr (VI)) from wastewater by magnetite nanoparticles. Procedia Technology. 2016; 24:585-94. Crossref.
- Mathew J, Joy J, George SC. Potential applications of nanotechnology in transportation: A review. Journal of King Saud University - Science. 2018.
- Bedoya PM, Tamayo CA. Caracterizacion de la cascara de naranja para suusocomo material bioadsorbente. Bistua. 2008; 6(1):1-23.
- Li J, Pan Y, Xiang C, Ge Q, Guo J. Low temperature synthesis of ultrafine a-Al2O3 powder by a simple aqueous sol-gel process. Ceramics International. 2006; 32(5):587-91. Crossref.
- Sadri M, Pedbeni A, Hossein H. Preparation of Biopolymeric Nanofiber Containing Silica and Antibiotic. Journal of Nanostructures. 2016; 6(1):96-100.
- Mohseni M, Gilani K, Mortazavi SA. Preparation and Characterization of Rifampin Loaded Mesoporous Silica Nanoparticles as a Potential System for Pulmonary Drug Delivery. Iranian Journal of Pharmaceutical Research. 2015; 14(1):27-34. PMid:25561909 PMCid:PMC4277616
- Alves V, Mosquetta R, Coelho N. Determination of cadmium in alcohol fuel using Moringa oleifera seeds as a biosorbent in an on-line system coupled to FAAS. Talanta. 2010; 80(3):1113-38. Crossref. PMid:20006064.
- Carmona S. Elaboracion y caracterizacion de peliculasdelgadas de oxido de aluminio: propiedadesopticas, estructurales y electricas. Instituto politecniconacional Mexico DF. 2008; p. 1-112.
- Skoog DA, Holler FJ, Nieman TA. Principios de analisis instrumental. Madrid McGraw-Hill. 2001; p. 122-50.
- Oickle A, Goertzen S, Hopper K, Abdalla Y, Andreas H. Standardization of the Boehm titration: Part II. Method of agitation, effect of filtering and dilute titrant. Carbon. 2010; 48(12):3313-22. Crossref.
- Vafakhah S, Bahrololoom M, Saeedikhani M. Removal of copper ions from electroplating effluent solutions with native corn cob and corn stalk and chemically modified corn stalk. Journal of Environmental Chemical Engineering. 2014; 2(1):356-61. Crossref.
- Vafakhah S, Bahrololoom ME, Saeedikhani M. Adsorption Kinetics of Cupric Ions on Mixture of Modified Corn Stalk and Modified Tomato Waste. Journal of Water Resource and Protection. 2016; 8(13):1238-50. Crossref.
- Ramos L, Jacome BL, Rodriguez AI. Adsorption of cadmium (II) from aqueous solution on natural and oxidized corn cob. Separation and Purification Technology. 2005; 45(1):41-9. Crossref.
- Alves C, Franca A, Oliveira L. Removal of phenylalanine from aqueous solutions with thermo-chemically modified corn cobs as adsorbents. LWT - Food Science and Technology. 2013; 51(1):1-8. Crossref.
- Sakulthaew C, Chokejaroenrat C, Poapolathep A. Hexavalent chromium adsorption from aqueous solution using carbon. Chemosphere. 2017; 184:1168-74. Crossref. PMid:28672698.
- Gupta V, Nayak A. Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles. Chemical Engineering Journal. 2012; 180:81-90. Crossref.
- Figueira M, Volesky B, Ciminelli V, Roddick F. Biosorption of metals in brown seaweed biomass. Water Research. 2000; 34(1):196-204. Crossref.
- Goyal P, Srivastava S. Characterization of novel Zeamays based biomaterial designed for toxic metals biosorption. Journal of Hazardous Materials. 2009; 172(2):1206-11. Crossref. PMid:19709812.
- Basso M, Cukierman A. Empleo de un biosorbente para el tratamiento de agua. Avancesen Energias Renovables y Medio Ambiente. 2003; 7:901-6.
- Rebollo J. Eliminacon de Cadmio (II) de efluentesurbanostratadosmedianteprocesos de bioadsorcion: El efectocompetitivo de otrosmetalespesados. 2012; p. 1-113.
- Bansal M, Singh D, Garg V, Rose P. Use of Agricultural Waste for the Removal of Nickel Ions from Aqueous Solutions: Equilibrium and Kinetics Studies. World Academy of Science, Engineering and Technology. 2009; 3(3):1-27.
- Garg U, Kaur M, Garg V, Sud D. Removal of Nickel (II) from aqueous solution by adsorption agricultural waste biomass using a response surface methodological approach. Bioresource Technology. 2008; 99(5):1325-31. Crossref. PMid:17383868.