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A. O. Ayeni ¹, O. A. Adeeyo ¹, A. Ayoola ¹

Affiliations
1 Department of Chemical Engineering, Covenant University, Ota, NG

Abstract

In this study, alkaline peroxide oxidation pretreatment was evaluated for sugarcane bagasse, a lignocellulosic biomass. By comparing the effects of NaOH-H₂O₂ and Ca(OH)₂ on pretreatments at specified reaction time periods (3, 6, 9, and 12 h) and reaction temperatures (60, 70, 80, and 90 h), optimum responses in term of cellulose content, hemicellulose solubilization, and lignin removal were established. Optimum pretreatment conditions of 80 °C reaction temperature, 3 h reaction time, and 30 mL/L of water hydrogen peroxide concentration (1%H₂O₂) solubilized 69.5%(w/w) hemicellulose for the sodium hydroxide peroxide (SHP) pretreatments, 75.8%(w/w) lignin removal was also achieved with 59.2%(w/w) cellulose retained in the solid fraction. In addition, the responses for the optimum conditions for the calcium hydroxide peroxide (CHP) pretreatments, the cellulose content, hemicellulose solubilization, and lignin removal were 50.3%, 66.6%, and 65.4%(w/w) respectively. Pretreatments showed both NaOH-H₂O₂ and Ca(OH)₂-H₂O₂ to be useful pretreatment agents for the disruption of the polysaccharide complex. The study also revealed that NaOH-H₂O₂ pretreatment stands as a better choice to Ca(OH)₂-H₂O₂ pretreatment.

Keywords

Pretreatment, Sugarcane Bagasse, Saccharum officinarium, Gravimetry.

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