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Preparation of Activated Carbons from Some Cellulosic Wastes and their Use in Removal of Oil Spills from Water Bodies


Affiliations
1 Department of Chemistry, Aleppo University, Syrian Arab Republic
 

Background/Objectives: Preparing of activated carbons from agricultural wastes and testing its removal efficiencies of organic waste such as oil that oil spills on water bodies are harmful to the environment and humans.

Methods/Statistical Analysis: The study involves the producing of activated carbon from wheat straw, uncooked and cooked corn cobs by using chemical activation method with 50 wt % phosphoric acid followed by carbonization in N2 atmosphere at 500¡ãC. Activated carbons were characterized by Fourier transform-infrared (FT-IR) spectroscopy and nitrogen adsorption/desorption isotherms.

Finding: Under certain process conditions, several active carbons with appropriate BET surface areas have been produced, reached 1343.75 m2/g and pore volumes 0.9106 cm3/g for cooked corn cob carbon.

Improvements/Application: The best oil adsorption capacity was shown by activated carbon prepared from cooked corn cob 5.25g oil/g sorbent.


Keywords

Oil Spill, Activated Carbon, Cellulosic Wastes.
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  • M. Hussein, A. A. Amer, I. I. Sawsan. Oil spill sorption using carbonized pith bagasse: trial for practical application. International Journal of Environmental Science & Technology. 2008; 5(2), 233-242.
  • B. Mungasatkit. Natural Adsorbents in Oil Spill Cleanup. Mahidol University for the degree of Master of Science, Appropriate Technology for Resource and Environmental Development. 2004, 1-178.
  • Sangeeta Chatterjee. Oil spill cleanup: role of environmental biotechnology. Applied Environmental Biotechnology: Present Scenario and Future Trends. 2015; 129-143.
  • R.V. Maulion, S.A. Abacan, G.G. Allorde, C.S. Umali. Oil spill adsorption capacity of activated carbon tablets from corncobs in simulated oil-water mixture. Asia Pacific Journal of Multidisciplinary Research. 2015; 3(5), 146-151.
  • S. M. Yakout, G. Sharaf El-Deen. Characterization of activated carbon prepared by phosphoric acid activation of olive stones. Arabian Journal of Chemistry. 2016.
  • Shabanzadeh. Production of activated carbon within the indirect gasification process. Master’s thesis within the Sustainable Energy Systems programmed. Department of Energy and Environment. Division of Energy Technology. Chalmers University of Technology. 2012; 1-52.
  • Mohd AdibYahya, Z. AL-Qodah, C.W. Zanariah Ngah. Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review. Renewable and Sustainable Energy Reviews. 2015; 218–235.
  • P.Y.L. Foo, L.Y. Lee. Preparation of activated carbon from PARKIA SPECIOSA pod by chemical activation. Proceeding of the World Congress on Engineering and Computer Science. 2010; 2, 20-22.
  • I.A.W. Tan, A.L. Ahmad, B.H. Hameed. Preparation of activated carbon from coconut husk: optimization study on removal of 2, 4, 6-trichlorophenol using response surface methodology. Journal of Hazardous Materials. 2008; 153(1-2), 709–717.
  • ASTM. F 726-99: Standard Test Method for Sorbent Performance of Adsorbents. 1999.
  • S.J. Gregg, K. S. W. Sing. Adsorption, surface area and porosity 2nd Edition 1982; 86(10), 1-957.
  • N.T. Abdel-Ghani, G.A. El-Chaghaby, M.H. El-Gammal, E.A. Rawash. Optimizing the preparation conditions of activated carbons from olive cake using KOH activation. New Carbon Materials. 2016; 31(5), 492-500.
  • K. Yujiao, Y. Qinyan, L. Dong, W. Yuwei, G. Baoyu. Preparation and characterization of activated carbons from waste tea by H3PO4 activation in different atmospheres for OXYTETRACYCLINE removal. Journal of the Taiwan Institute of Chemical Engineers. 2017; 71, 494-500.

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  • Preparation of Activated Carbons from Some Cellulosic Wastes and their Use in Removal of Oil Spills from Water Bodies

Abstract Views: 244  |  PDF Views: 143

Authors

Rakan Barhoum
Department of Chemistry, Aleppo University, Syrian Arab Republic
Hadeel Tabbakh
Department of Chemistry, Aleppo University, Syrian Arab Republic

Abstract


Background/Objectives: Preparing of activated carbons from agricultural wastes and testing its removal efficiencies of organic waste such as oil that oil spills on water bodies are harmful to the environment and humans.

Methods/Statistical Analysis: The study involves the producing of activated carbon from wheat straw, uncooked and cooked corn cobs by using chemical activation method with 50 wt % phosphoric acid followed by carbonization in N2 atmosphere at 500¡ãC. Activated carbons were characterized by Fourier transform-infrared (FT-IR) spectroscopy and nitrogen adsorption/desorption isotherms.

Finding: Under certain process conditions, several active carbons with appropriate BET surface areas have been produced, reached 1343.75 m2/g and pore volumes 0.9106 cm3/g for cooked corn cob carbon.

Improvements/Application: The best oil adsorption capacity was shown by activated carbon prepared from cooked corn cob 5.25g oil/g sorbent.


Keywords


Oil Spill, Activated Carbon, Cellulosic Wastes.

References