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Mishra, R. K.
- Modified Flory Theory and Pseudo Spinodal Equation of State for the Evaluation of Isothermal Compressibility, Isentropic Compressibility, Internal Pressure and Pseudo Gruneisen Parameter of Binary Liquid Mixtures at Elevated Pressure
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Authors
Affiliations
1 Department of Chemistry, University of Allahabad, Allahabad-211002, IN
2 Department of Electronics, E.C.C., Allahabad, IN
1 Department of Chemistry, University of Allahabad, Allahabad-211002, IN
2 Department of Electronics, E.C.C., Allahabad, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 28, No 1 (2006), Pagination: 20-28Abstract
Flory's statistical theory has been extended for the computation of internal pressure, isentropic compressibility, isothermal compressibility and Pseudo Gruneisen parameter of binary mixture nitrobenzene+benzene at pressure up to 10 MPa and at two different temperatures (293.15K, 303.15K & 313.15K). For a comparative study of the isothermal compressibility of this system, equation of state based on the psuedo spinodal hypothesis developed by Baonza et al has also been utilized to deduce the isothermal compressibility of this mixture. The computed values of Pint, βT, βs and Γ have been compared with the experimental findings available in literature. Satisfactory agreement has been found between experimental and theoretical values.- Acoustic Method for the Estimation of Effective Debye Temperature of Binary and Ternary Liquid Mixtures
Abstract Views :237 |
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Authors
Affiliations
1 Department of Chemistry, University of Allahabad, Allahabad-211002, IN
1 Department of Chemistry, University of Allahabad, Allahabad-211002, IN