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Sharma, Arun Kumar
- Ultrasonic Studies of Cu (II) Soaps Derived from Groundnut and Seasame Oils
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Authors
Affiliations
1 Department of Chemistry, S.P.C. Govt. College Ajmer-305001, IN
2 Department of Chemistyr, S.D. Govt. College Beawar-305901, IN
1 Department of Chemistry, S.P.C. Govt. College Ajmer-305001, IN
2 Department of Chemistyr, S.D. Govt. College Beawar-305901, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 39, No 3 (2017), Pagination: 92-99Abstract
Ultrasonic speed have been measured in pure and binary mixtures containing copper soaps derived from groundnut and sesame oils in 20 % and 40% methanol benzene mixture. From these values, the specific acoustic impedance, adiabatic compressibility, intermolecular free length, apparent molar compressibility, molar sound velocity, primary solvation number have been calculated. The results have been fitted to Masson equation. The results have been explained on the basis of intermolecular interactions.Keywords
Copper Soaps, Methanol, Groundnut Oil, Sesame Oil, Ultrasonic Speed.Full Text
References
- Pawar N.R. and Chimankar O.P., Comparative study of ultrasonic absorption and relaxation behavior of polar solute and non-polar solvent, J. Pure Appl. Ultrason. 34 (2012) 49-52.
- Sivakumar V., Verma R.V., Rao P.G. and Swaminathan G., Studies on the use of power ultrasound in solid liquid myrobal an extraction process. J. Clean Prod. 15 (2007) 1813-1818.
- Nath G., Ultrasonic Study of Binary Mixture of Acetone with Bromo benzene and Chloro benzene at Different Frequencies, Chem. Sci. Trans. 1(3) (2012) 516-521.
- Moharatha D., Talukdar M., Roy G.S. and Dash U.N., Evaluation of acoustic parameters of halides of alkali metals and Ammonium in aqueous and aqueous Dextran solutions at 298.15K, Researcher 3 (2011) 6-12.
- Palani R. and Balakrishnan S., Acoustical properties of ternary mixtures of 1-alkanols in di-isopropyl ether and 2, 2, 2-trifluoroethanol mixed solvent, Indian J. Pure Appl. Phys. 48 (2010) 644-650.
- Singh G. and Banipal T.S., Partial molar adiabatic compressibilities and viscosities of some amino acids in aqueous glycerol solutions at 298.15K, Indian J. Chem. 47A (2008) 1355.
- Sharma R., Bhutra R. and Khan S., Micellar Behaviour of Copper Surfactants Derived from Fresh (Untreated) Sesame Oil and Used (Treated at High Temperature) Sesame Oil, Tenside Surf Det. 47 106-112.
- Das J., Dash K., Swain S.K. and Swain N., Ultrasonic investigation in a polar-polar system, methyl-Isobutyl Ketone and aliphatic alcohols, J. Mol. Liquids. 81 (1999) 163-179.
- Ranganayakulu S.V., Reddy C.S. and Reddy D.L., Ultrasonic studies of the binary mixtures of ethyl acetateand cresols-application of Kosower and Dimroth treatments, Mat. Chem. Phys. 90 (2005) 213-216.
- Kanhekar S.R., Pravina P. and Govind K.B., Thermodynamic properties of electrolytes in aqueous solutions of glycine at different temperatures, Indian J. Pure Appl. Phys. 48 (2010) 95-99.
- Fort R.J. and Moore W.R., Adiabatic compressibilities of binary liquid mixtures, Trans. Faraday Soc. 61 (1965) 2102-2111.
- Banipal P.K. Chakal A.K. and Banipal T.S., Studies on volumetric properties of some saccharides in aqueous potassium chloride solutions over temperature range (288.15-318.15 K), J. Chem. Thermodynamic. 41 (2009) 452-483.
- Savaroglu G. and Ozdemir M., Apparent molar volume and apparent molar isentropic compressibility of glycerol in fructose water at different temperature, J. Mol. Liquids. 137 (2008) 51-57.
- Syal V.K., Chauhan S. and Gautam R., Ultrasonic velocity measurements of carbohydrates in binarymixtures of DMSO + H2O at 25°C, Ultrasonics. 36 (1998) 619621.
- Ali A., Hyder S. and Nain A.K., Intermolecular and ion solvent interaction of sodium iodide and potassium iodide in dimethyl formamide + I-propanol mixtures at 303K, J. Pure Appl. Ultrason. 21 (1999) 127-131.
- Punitha S. and Uvarani R., Physico-chemical studies on some saccharides in aqueous cellulose solutions at different temperatures- Acoustical and FTIR analysis J. Saudi Chem. Soc. 18 (2014) 657-665.
- Kagathara V.M., Sanariya M.R. and Parsania P.H., Sound velocity and molecular interaction studies on chloroepoxy resins solutions at 30°C, Eur. Polym. J. 36 (2000) 2371-2374.
- Dash A.K. and Paikaray R., Acoustical study on ternary mixture of dimethyl acetamide (DMAC) in diethyl ether and isobutyl methyl ketone at different frequencies, Phys.Chem. Liq. 51(6) (2013) 749-763.
- Singh S. and Bahadur I., Density and speed of sound of 1-ethyl-3-methylimidazolium ethylsulphate with acetic or propionic acid at different temperatures, J. Mol. Liq. 199 (2014) 518-523.
- Jahagirdar B.V., Arbad. B.R., Walvekar. A.A., Shankarwer A.G. and Lande M., Studies in partial molar volumes, partial molar compressibilities and viscosity Bcoefficients of caffeine in water at four temperatures, J. mol. liq. 85 (2000) 361-373.
- Studies of Ultrasonic and Acoustic Parameters of Cu (II) Surfactant of Fresh and Treated Sesame and Soyabean Oils at High Temperature for Different Time
Abstract Views :167 |
PDF Views:0
Authors
Affiliations
1 Department of Chemistry, Rajesh Pilot Government Polytechnic College, Dausa-303303, IN
2 S.P.C. Government College, Ajmer-305001, IN
3 Government P.G. College, Jhalawar-326001, IN
1 Department of Chemistry, Rajesh Pilot Government Polytechnic College, Dausa-303303, IN
2 S.P.C. Government College, Ajmer-305001, IN
3 Government P.G. College, Jhalawar-326001, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 40, No 2 (2018), Pagination: 46-51Abstract
Colloid chemical behavior and micellar characteristics of Cu (II) soaps derived from sesame and soyabean oils, (fresh oils and treated for 15 and 60 min.) at high temperature in benzene have been investigated and verified by ultrasonic velocity measurement. From these values, the specific acoustic impedance Z, adiabatic compressibility βad, intermolecular free length Lf, apparent molar compressibility Øk, molar sound velocity R, primary solvation number Sn have been calculated. The results have been analyzed in terms of Masson's equation. The results have been explained on the basis of solute-solvent interactions. The decrease in β and Lf with increasing concentration of the complex is indicating that there is sufficient solute- solvent interaction due to which micellar alignment is considerably affected.Keywords
Copper Surfactants, Benzene, Sesame Oil, Soyabean Oil, Ultrasonic, Solute-Solvent Interaction.Full Text
References
- Saxena M., Sharma R. and Sharma A.K., Micellar Features of Cu (II) surfactants derived from edible oils "ISBN 978-620-2-01906-4" LAP Lambert Academic Publishing Germany (2017).
- Sharma A.K., Saxena M. and Sharma R., Synthesis, spectroscopic and fungicidal studies of Cu (II) soaps derived from groundnut and sesame oils and their urea complexes, Bulletin of Pure and Applied Sciences, 36(2) (2017) 26-37.
- Khan S., Sharma R. and Sharma A.K., Acoustic studies and other acoustic parameters of Cu(II) soap derived from nonedible neem oil (azadirecta indica), in non-aqueous media at 298.15, Acta Ac united Ac. 104 (2018) 277-283
- Sharma A.K., Saxena M. and Sharma R., Synthesis, spectroscopic and biocidal activities of environmentally safe Agrochemicals, J. Biochem. Tech. 7(3) (2018) 1139-1147.
- Tank P., Sharma R. and Sharma A.K., Studies of Ultrasonic and acoustic parameters of complexes derived from Copper (II) surfactant of mustard oil with N and S atoms containing ligands in non-aqueous media (benzene) at 303.15 K. J. Acous. Soc. Ind. 44(2) (2017) 87-99.
- Bhutra R., Sharma R. and Sharma, A.K., Viscometric and CMC studies of Cu(II) surfactants derived from untreated and treated groundnut and mustard oils in non-aqueous solvent at 298.15 K, J. Inst. Chemists. 90 (2017) 29-47.
- Sharma S., Sharma R. and Sharma A.K., Synthesis, Characterization, and thermal degradation of Cu (II) Surfactants for sustainable green chem, Asian J. Green Chem. 2(2) (2017) 129-140.
- Sharma S., Sharma R., Heda L.C. and Sharma, A.K., Kinetic parameters and photo degradation studies of copper soap derived from soybean oil using ZnO as a Photo catalyst in solid and solution Phase, J. Inst. Chemists. 89(4) (2017) 119-136.
- Tank P., Sharma R. and Sharma A.K., A pharmaceutical approach and antifungal activities of copper Soaps with their N and S donor complexes derived from mustard and soyabean oils, Glob. J. Pharmaceu. Sci. 3(4) (2017) GJPPS.MS.ID.555619.
- Khan S., Sharma R. and Sharma A.K., Ultrasonic studies of Cu (II) Soap derived from seed oil of Pongamia pinnata (Karanj), in non-aqueous binary and ternary systems at 298.15K. Malaysian J. Chem. 19(2) (2017) 99-110.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of copper soaps urea complexes derived from mustard and soyabean oils. J. Phy. Sci. (2018) (Accepted).
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) soaps derived from mustard and soybean oils. J. Pure Appl. Ultrason, 39(3) (2017) 92-99.
- Tank P., Sharma R. and Sharma A.K., Micellar features and various interactions of copper soap complexes derived from edible mustard oil in benzene at 303.15 K. Curr. Phy. Chem. 8(1) (2018) 46-57.
- Sharma R. and Sharma A.K., Natural edible oils: comparative health aspects of sesame, coconut, mustard (rape seed) and groundnut (peanut) a biomedical approach, Biomed. J. Sci. Tech. Res. 1(5) (2017) BJSTR.MS.ID.000441.
- Tank P., Sharma A.K. and Sharma R., Thermal behaviour and kinetics of copper (II) soaps and complexes derived from mustard and soyabean oil, J. Anal. Pharm. Res. 4(2) (2017) 1-5.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) Soaps derived from Groundnut and Sesame oils, Tenside. Surf. Det. 55(2) (2018) 127-134.
- Bhutra R., Sharma R. and Sharma A.K., Synthesis, Characterization and fungicidal activities of Cu (II) surfactants derived from groundnut and mustard oils treated at high temperatures, J. Inst. Chemists. 90(3) (2018) 66-80.
- Sharma A.K., Sharma R. and Saxena M., Biomedical and antifungal application of Cu(II) soaps and its urea complexes derived from various oils, Open Access J. Trans. Med. Res. 2(2) (2018) 40-43.
- Sharma A.K., Sharma S. and Sharma R., Thermal degradation of Cu (II) metallic soaps and their Characterizations. A pharmaceutical application, Chro. Phar Sci., 1(5) (2017) 312-319.
- Sharma A.K., Saxena M. and Sharma R., Acoustic studies of copper Soap-urea complexes derived from groundnut and seasam oils. J. Phy. Studies, 21(4) (2017) 4601-6.
- Acoustic Parameters and Studies of Complexes Containing Copper Surfactants with Substituted 2-Amino-6-Chloro Benzothiazole
Abstract Views :252 |
PDF Views:0
Authors
Affiliations
1 Department of Chemistry, Government P.G. College, Jhalawar-326001, IN
2 Department of Chemistry, S.P.C. Government College, Ajmer-305001, IN
1 Department of Chemistry, Government P.G. College, Jhalawar-326001, IN
2 Department of Chemistry, S.P.C. Government College, Ajmer-305001, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 41, No 3 (2019), Pagination: 63-68Abstract
Ultrasonic speed and density parameters have been measured in binary and ternary systems containing complexes of copper surfactants (caprylate, caprate, and laurate) with substituted 2-amino-6-chloro benzothiazole in 80% and 40% benzene-methanol mixture at constant temperature using thermostatic water bath. From these values, the specific acoustic impedance Z, adiabatic compressibility , intermolecular free length Lf, apparent molar compressibility φk, have been calculated. The results have been explained on the basis of intermolecular interactions and indicate that there is sufficient solute-solvent interaction due to which micellar alignment is considerably affected. The decrease in adiabatic compressibility β and intermolecular free length Lf of the copper surfactant complex solution with increasing concentration of copper surfactant complex in 80% and 40% benzene methanol has been observed which suggest that the non-polar long chains or lypophilic segment of the molecule in the solution are enveloped by a layer of solvent molecules bound and oriented towards lypophilic end. The orientation of the solvent molecules around the solutes may be due to the influence of electrostatic fields of solutes and results in the increase in the internal pressure and in lowering the compressibility of the solution i.e. the solution becomes harder to compress.Keywords
Acoustic Parameters, Benzothiazole, Copper, Surfactants.Full Text
References
- Fort R.J. and Moore W.R., Adiabatic compressibilities of binary liquid mixtures, Trans. Faraday Soc. 61 (1965) 2102-2111.
- Bhutra R., Sharma R. and Sharma A.K., Studies of ultrasonic and acoustic parameter of copper (II) surfactants of groundnut and soyabean oils treated at different temperatures. J Acoust. Soc. India, 25(1) (2018) 42-52.
- Banipal P.K., Chakal A.K. and Banipal T.S., Studies on volumetric properties of some saccharides in aqueous potassium chloride solutions over temperature range (288.15-318.15 K), J. Chem. Thermodynamic. 41 (2009) 452-483.
- Khan S., Sharma R. and Sharma A.K., Acoustic studies and other acoustic parameters of Cu (II) soap derived from nonedible Neem oil (azadirectaindica), in non-aqueous media at 298.15, Acta Ac united Acust. 104 (2018) 277-283.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) Soaps derived from groundnut and Sesame oils, Tenside. Surf. Det. 55(2) (2018) 127-134.
- Savaroglu G. and Ozdemir M., Apparent molar volume and apparent molar isentropic compressibility of glycerol in fructose water at different temperature, J. Mol. Liq. 137 (2008) 51-57.
- Tank P., Sharma R. and Sharma A.K., Studies of Ultrasonic and acoustic parameters of complexes derived from copper (II) surfactant of mustard oil with N and S atoms containing ligands in non-aqueous media (benzene) at 303.15 K. J. Acous. Soc. India 44(2) (2017) 87-99.
- Bhutra R., Sharma R. and Sharma A.K., Studies of ultrasonic and acoustic parameters of copper (II) surfactant of sesame and soyabean oils treated at different temperatures. J. Pure Appl. Ultrason. 40 (2018) 46-51.
- Khan S., Sharma R. and Sharma A.K., Ultrasonic studies of Cu(II) soap derived from seed oil of pongamiapinnata (Karanj), in non-aqueous binary and ternary systems at 298.15K. Malaysian J. Chem. 19(2) (2017) 99-110.
- Sharma R., Gangwal A. and Sharma A.K., Copper soap-complexes: micellar and biological analysis LAP LAMBERT Academic Publishing: Germany (2018).
- Syal V.K., Chauhan S. and Gautam R., Ultrasonic velocity measurements of carbohydrates in binarymixtures of DMSO + H2O at 25°C, Ultrasonics 36 (1998) 619-621.
- Ali A., Hyder S. and Nain A.K., Intermolecular and ion solvent interaction of sodium iodide and potassium iodide in dimethyl formamide + I-propanol mixtures at 303K, J. Pure Appl. Ultrason. 21(1999) 127-131.
- Sharma A.K., Saxena M. and Sharma R., Acoustic Studies of copper soap urea complexes derived from groundnut and sesame oils. J. Phy. Stud. 21(4) (2017) 4601-6.
- Punitha S. and Uvarani R., Physico-chemical studies on some saccharides in aqueous cellulose solutions at different temperatures- acoustical and FTIR analysis. J. Saudi Chem. Soc. 18 (2014) 657-665.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of copper soaps urea complexes derived from mustard and soyabean oils. J. Phy. Sc. 29(3) (2018) 67-82.
- Masson D.O., Solute molecular volumes in relation to solvation an ionization, Philos. Mag. 8 (1929) 218-235.
- Kagathara V.M., Sanariya M.R. and Parsania P.H., Sound velocity and molecular interaction studies on chloroepoxy resins solutions at 30°C, Eur. Polym. J. 36 (2000) 2371-2374.
- Dash A.K. and Paikaray R., Acoustical study on ternary mixture of dimethyl acetamide (DMAC) in diethyl ether and isobutyl methyl ketone at different frequencies, Phys. Chem. Liq. 51(6) (2013) 749-763.
- Sharma A.K., Saxena M. and Sharma R., Ultrasonic studies of Cu (II) Soaps derived from mustard and soybean oils. J. Pure Appl. Ultrason. 39(3) (2017) 92-99.
- Singh S. and Bahadur I., Density and speed of sound of 1-ethyl-3-methylimidazolium ethylsulphate with acetic or propionic acid at different temperatures, J. Mol. Liq. 199 (2014) 518-523.