Journal of Pure and Applied Ultrasonics

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Excess Thermo Acoustical Parameters of Binary Mixture Ammonium Hydroxide and Ethanol


Affiliations
1 Department of Electronics, Anand Niketan College, Warora-442 914, India
2 Department of Physics, L.T. College, Wani-445 304, India
3 Department of Physics, Shivaji Science College, Amravati-444 602, India
4 Department of Physics, RTM Nagpur University, Nagpur-440 033, India
 

The ultrasonic velocity (U) density (ρ) and viscosity (η) of binary liquid mixture of Ammonium Hydroxide with ethanol have been measured over the entire range of compositions at the temperature 313K and frequency 1MHz. The observed basic experimental data have been utilized to evaluate some of the derived thermo acoustic parameters such as free volume, internal pressure, relaxation time and Gibbs free energy. The behavior of these parameters and the excess values of free volume, Internal pressure, relaxation time, and Gibbs free energy were evaluated with composition of the mixture and have been discussed in terms of nature and strength of molecular interactions between the constituents.

Keywords

Ultrasonic Velocity, Acoustical Parameters, Molecular Interactions.
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  • Excess Thermo Acoustical Parameters of Binary Mixture Ammonium Hydroxide and Ethanol

Abstract Views: 168  |  PDF Views: 2

Authors

V. D. Bhandakkar
Department of Electronics, Anand Niketan College, Warora-442 914, India
V. R. Bhat
Department of Physics, L.T. College, Wani-445 304, India
A. W. Asole
Department of Physics, Shivaji Science College, Amravati-444 602, India
O. P. Chimankar
Department of Physics, RTM Nagpur University, Nagpur-440 033, India

Abstract


The ultrasonic velocity (U) density (ρ) and viscosity (η) of binary liquid mixture of Ammonium Hydroxide with ethanol have been measured over the entire range of compositions at the temperature 313K and frequency 1MHz. The observed basic experimental data have been utilized to evaluate some of the derived thermo acoustic parameters such as free volume, internal pressure, relaxation time and Gibbs free energy. The behavior of these parameters and the excess values of free volume, Internal pressure, relaxation time, and Gibbs free energy were evaluated with composition of the mixture and have been discussed in terms of nature and strength of molecular interactions between the constituents.

Keywords


Ultrasonic Velocity, Acoustical Parameters, Molecular Interactions.

References