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Authors
Affiliations
1 Bukhara State University, Research laboratory "Chemistry of coordination compounds" named after Academician N.A.Parpiev, UZ
2 Institute of Bioorganic Chemistry named after O.S. Sodikov
Source
Nano Science & Nano Technology: An Indian Journal, Vol 16, No 6 (2022), Pagination: 1 - 4
Abstract
This work presents the results of the study and analysis of the electronic-structural and coordination properties of various forms of glutamine, using quat-chemical calculation, results of synthesis and study of the composition, structure of new single- and multi-ligand mono- and binuclear glutamine complexes of ions of some 3d metals by methods of quantum chemical calculation, IR, ESR spectroscopy and their biological activity.
Keywords
Density functional theory; Zwitterion; Molecule; Charge; Structure; Donor-acceptor interaction; Quantum-chemical calculations; Electron-paramagnetic resonance
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References
- Deschamps P, Zerrouk N, Nicolis I, et al. Copper (II)–l-glutamine complexation study in solid state and in aqueous solution. Inorganica chimica acta. 2003;353:22-34.
- Schveigkardt JM, Rizzi AC, Piro OE, et al. Structural and Single Crystal EPR Studies of the Complex Copper l‐Glutamine: A Weakly Exchange‐Coupled System with syn‐anti Carboxylate Bridges. European Journal of Inorganic Chemistry.2002(11):2913-9.
- Arena G, Conato C, Contino A, et al. Cu (II)-L-glutamine and L-asparagine binary complexes. A thermodynamic and spectroscopic study. ANNALI DI CHIMICA-ROMA-. 1998;88:1-2.
- Baran EJ, Viera I, Torre MH. Vibrational spectra of the Cu (II) complexes of L-asparagine and L-glutamine. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.2007;66(1):114-7.
- John L, Joseyphus RS, Dasan A et al. Protein binding and cytotoxicity activities of glutamine based metal complexes. Journal of Molecular Structure. 2021;1240:130540.
- Mardonov UM, Ganiev BSh, et al. Study by methods of quantum-chemical calculation and EPR spectroscopy of electronic- structural and coordination properties of various forms of glutamine. Universum: chemistry and biology. 2022;92:49-54.
