Nano Science & Nano Technology: An Indian Journal

Open Access Open Access  Restricted Access Subscription Access

Study of IR, Esr-Spectroscopy, Structural and Biological Properties of 3D Metal Ion Complexes With Glutamine


Affiliations
1 Bukhara State University, Research laboratory "Chemistry of coordination compounds" named after Academician N.A.Parpiev, Uzbekistan
2 Institute of Bioorganic Chemistry named after O.S. Sodikov
 

This work presents the results of the study and analysis of the electronic-structural and coordination properties of various forms of glutamine, using quat-chemical calculation, results of synthesis and study of the composition, structure of new single- and multi-ligand mono- and binuclear glutamine complexes of ions of some 3d metals by methods of quantum chemical calculation, IR, ESR spectroscopy and their biological activity.


Keywords

Density functional theory; Zwitterion; Molecule; Charge; Structure; Donor-acceptor interaction; Quantum-chemical calculations; Electron-paramagnetic resonance
User
Notifications
Font Size

  • Deschamps P, Zerrouk N, Nicolis I, et al. Copper (II)–l-glutamine complexation study in solid state and in aqueous solution. Inorganica chimica acta. 2003;353:22-34.

  • Schveigkardt JM, Rizzi AC, Piro OE, et al. Structural and Single Crystal EPR Studies of the Complex Copper l‐Glutamine: A Weakly Exchange‐Coupled System with syn‐anti Carboxylate Bridges. European Journal of Inorganic Chemistry.2002(11):2913-9.

  • Arena G, Conato C, Contino A, et al. Cu (II)-L-glutamine and L-asparagine binary complexes. A thermodynamic and spectroscopic study. ANNALI DI CHIMICA-ROMA-. 1998;88:1-2.

  • Baran EJ, Viera I, Torre MH. Vibrational spectra of the Cu (II) complexes of L-asparagine and L-glutamine. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.2007;66(1):114-7.

  • John L, Joseyphus RS, Dasan A et al. Protein binding and cytotoxicity activities of glutamine based metal complexes. Journal of Molecular Structure. 2021;1240:130540.

  • Mardonov UM, Ganiev BSh, et al. Study by methods of quantum-chemical calculation and EPR spectroscopy of electronic- structural and coordination properties of various forms of glutamine. Universum: chemistry and biology. 2022;92:49-54.


Abstract Views: 84

PDF Views: 1




  • Study of IR, Esr-Spectroscopy, Structural and Biological Properties of 3D Metal Ion Complexes With Glutamine

Abstract Views: 84  |  PDF Views: 1

Authors

Ganiev Bakhtiyor
Bukhara State University, Research laboratory "Chemistry of coordination compounds" named after Academician N.A.Parpiev, Uzbekistan
U.M. Mardonov
Bukhara State University, Research laboratory "Chemistry of coordination compounds" named after Academician N.A.Parpiev, Uzbekistan
J.M. Ashurov
Institute of Bioorganic Chemistry named after O.S. Sodikov

Abstract


This work presents the results of the study and analysis of the electronic-structural and coordination properties of various forms of glutamine, using quat-chemical calculation, results of synthesis and study of the composition, structure of new single- and multi-ligand mono- and binuclear glutamine complexes of ions of some 3d metals by methods of quantum chemical calculation, IR, ESR spectroscopy and their biological activity.


Keywords


Density functional theory; Zwitterion; Molecule; Charge; Structure; Donor-acceptor interaction; Quantum-chemical calculations; Electron-paramagnetic resonance

References