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Simple Ions vis-à-vis Ion Pairs and Ion Triplets for Electrolytes in Pure as Well as Mixed Non-Aqueous Solvents
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The regions of both ideal and non-ideal behaviour of electrolyte solutions containing simple ions, ion pairs or undissociated molecules, and ion triplets have been analyzed theoretically in terms of measurable electrical properties. Methods have been devised to obtain the values of different equilibrium constants and species concentrations. Effects of temperature and solvent composition on the thermodynamic properties ΔGφ, ΔHφ and ΔSφ and evaluation techniques of these quantities have been discussed. Molar conductance of some ion-triplets has also been evaluated.
Keywords
Molar Conductance of Associated Ions, Ionic Strength, Ion Triplet, Ion Association Constant, Mixed Non-Aqueous Solvents.
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