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Review on Beneficiation of Indian Coal Using Solvents


Affiliations
1 Department of Chemical Engineering, Jadavpur University, West Bengal, Kolkata, India
 

It is well known that Coal is an important fossil fuel and is used as a major source of energy in power plants and blast furnaces, but minerals in coal inhibit the effective utilization of coals. These are kind of troublesome materials in the cumbustors by forming the ash during combustion of coal. Industrial demand of coal with minimum ash content so that it can be efficiently used in metallurgical process, or, power plants. This paper reviews the removal of ash-forming minerals of coal using solvents by chemical techniques. Solvents, like N-Methyl-2-pyrrolidone (NMP), 1-methyl naphthalene (MN), Dimethylformamide (DMF), Dimethyl sulfoxide (DMSO) can be used to reduce the ash content of coal. However, polar solvents have been proved to extract greater amounts of coal and reduce ash to a greater extent than non-polar solvents, particularly for lower rank or sub-bituminous coals. However, if non-polar solvents are used, then traces of polar additives can also increase the extraction of coal as well as cause greater reduction of the ash content. The degree of ash reduction depends not only on the solvent used, but also on the extraction temperature, time and rank of coals.

Keywords

Coal Rank, Ash-Less Coal, Mild Condition, Binding Oil, Cost-Effective Solvent, Thermal Extraction.
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  • i. Bhattacharyya, R.N., A.K. Muza, and G.G. Sarkar, "Role 0f; Operating Variables in Oil Agglomeration of Coal", Aaalomeration Seventv Seven, 2, 931938, (1977).
  • ii. Liu, Y.A., Editor, Phvsical Cleanina of CoaL Chapter 6, Marcel1 Dekker, New-York, (1982).
  • iii. Kashimura, N., Takanohashi,T., Saito,I., Upgrading the Solvent Used for the Thermal Extraction of Sub-Bituminous Coal, Energy & Fuels 2006, 20, 2063-2066
  • iv. Kim,S.D., Woo,K.J., Jeong, S.K., Rhim, Y.J., Lee, S.H., Production of low ash coal by thermal extraction with N-methyl-2-pyrrolidinone, Korean J. Chem. Eng., 25(4), 758-763 (2008)
  • v. Li, C., Ashida, S., Iino, M., Coal Dissolution by Heat Treatments in N-Methyl-2- pyrrolidinone, 1,4,5,8,9,10-Hexahydroanthracene, and Their Mixed Solvents: A Large Synergistic Effect of the Mixed Solvents, Energy & Fuels 2000, 14, 190-196
  • vi. Makgato, M.H., Moitsheki, L.J., Shoko, L., Kgobane, B.L., Morgan, D.L., Focke, W.W., Alkali assisted coal extraction with polar aprotic solvents, Fuel Processing Technology (2009),doi:10.1016/j.fuproc.2008.12.016
  • vii. Okuyama, N., Komatsu, N., Shigehisa, T., Kaneko, T., Tsuruya, S., Hyper-coal process to produce ash-free coal, Fuel Processing Technology 85(2004), 947-967
  • viii. Rahman, M., Samanta, A., Gupta, R., Production and characterization of ash free coal from low-rank Canadian coal by solvent extraction, Fuel Processing Technology 115 (2013), 88–98
  • ix. Shui, H., Wang, Z., Gao, J., Examination ofthe role of CS2 in the CS2/NMP mixed solvents to coal extraction, Fuel Processing Technology 87 (2006), 185 – 190
  • x. Steel, K.M., Patrick, J.W., The production of ultra clean coal by chemicaldemineralization, Fuel 80(2001), 2019-2013
  • xi. Takahashi, K., Noringa, K., Masui, Y., Iino, M., Effect of addition of various salts on coal extraction with carbon disulfide/Nmethyl- 2-pyrrolidinone mixed solvent, Energy & Fuels, 2001, 15, 141-146
  • xii. Timpe, R.C., Knudson, C.L., Mack, P.,Beneficiation of a Bituminous and a Lignite coal by Agglomeration using novel binding oils
  • xiii. Yoshida, T., Takanohashi, T., Sakanishi, K., Saito, I., Fujita, M., Mashimo, K., The effect of extraction condition on hyper-coal production (1)-under room-temperature filtration, Fuel, 81, 2002, 1463-1469 12. Yoshida, T., Li, C. Takanohashi, T., Matsumura, A., Sato. S., Saito, I., Effect of extraction condition on hyper-coal production (1)-effect of polar solvents under hot filtration, Fuel Processing Technology, 86, 2004, 61-72.
  • xiv. H.Shui, K.Norinaga, M.lino, Energy Fuels 16 (2002) 69.
  • xv. A. Marzec, Towards an understanding of coal structure: a review, Fuel process. Technol. 77-78 (2002) 25-32.
  • xvi. A. Marzec, M. Jozwa, K. Belej, M. Sobkowiak, Bituminous coal extraction in terms of electron-donor and -acceptor interactions in the solvent/coal system, Fuel process. Technol. 2 (1979) 35-44.
  • xvii. P.J. Hall, H. Marsha, K.M. Thomas, Solvent induced Swellling of coals to study macromolecular structure,Fuel 67 (1988) 863-865.
  • xviii. Song c: Schobert, H.H. Fuel process technol. 1993,34,157.
  • xix. Yoshida, T., Li, C. Takanohashi, T., Matsumura, A., Sato. S., Saito, I., Effect of extraction condition on hyper-coal production (1)-effect of polar solvents under hot filtration, Fuel Processing Technology, xx. 86, 2004, 61-72.

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  • Review on Beneficiation of Indian Coal Using Solvents

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Authors

Rohit Kumar
Department of Chemical Engineering, Jadavpur University, West Bengal, Kolkata, India
Chanchal Mondal
Department of Chemical Engineering, Jadavpur University, West Bengal, Kolkata, India
Sujata Sardar
Department of Chemical Engineering, Jadavpur University, West Bengal, Kolkata, India

Abstract


It is well known that Coal is an important fossil fuel and is used as a major source of energy in power plants and blast furnaces, but minerals in coal inhibit the effective utilization of coals. These are kind of troublesome materials in the cumbustors by forming the ash during combustion of coal. Industrial demand of coal with minimum ash content so that it can be efficiently used in metallurgical process, or, power plants. This paper reviews the removal of ash-forming minerals of coal using solvents by chemical techniques. Solvents, like N-Methyl-2-pyrrolidone (NMP), 1-methyl naphthalene (MN), Dimethylformamide (DMF), Dimethyl sulfoxide (DMSO) can be used to reduce the ash content of coal. However, polar solvents have been proved to extract greater amounts of coal and reduce ash to a greater extent than non-polar solvents, particularly for lower rank or sub-bituminous coals. However, if non-polar solvents are used, then traces of polar additives can also increase the extraction of coal as well as cause greater reduction of the ash content. The degree of ash reduction depends not only on the solvent used, but also on the extraction temperature, time and rank of coals.

Keywords


Coal Rank, Ash-Less Coal, Mild Condition, Binding Oil, Cost-Effective Solvent, Thermal Extraction.

References