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Prabha, Shashi
- Synthesis and Hydrolysis of Phosphoric Diamide without Seeking C-N-P Protonation by Acid
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Authors
Affiliations
1 Gwalior Engineering College, Maharajpura, Airport Road, Gwalior (M.P.), IN
2 School of Studies in Chemistry, Jiwaji University, Gwalior (M.P.), IN
1 Gwalior Engineering College, Maharajpura, Airport Road, Gwalior (M.P.), IN
2 School of Studies in Chemistry, Jiwaji University, Gwalior (M.P.), IN
Source
Asian Journal of Research in Chemistry, Vol 4, No 9 (2011), Pagination: 1378-1380Abstract
Phosphoric bis-(o-Methoxyphenyl amide) chloride, a C-N-P containing ester, on kinetic examination exhibited a rate maximum (via the Neutral form only) at 4.0 M-HCl and gave second-order kinetic rate coefficients during hydrolysis in the acid range, 0.01-7.0M HCl at 40(± 0.5)°C. In the low acid range Zwitterionic species while in the higher acid range the undissociated form have been assessed as the major contributory reactive forms, undergoing bimolecular (Arrhenius Parameters) hydrolysis with P-N bond fission, The synthesis of the bis-amide was possible by the phosphorylation procedure and identification of the product was achieved by elemental analysis, and 31P NMR study in particular.Keywords
Phosphoric Bis-Amide, Undissociated Form, Hydrolysis, Synthesis.- Synthesis, Identification of Some P-Chiral Organic Phosphoramidates and Their Inhibitory Action Towards Enzymes
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Authors
Affiliations
1 School of Studies in Chemistry, Jiwaji University, Gwalior-474011, IN
1 School of Studies in Chemistry, Jiwaji University, Gwalior-474011, IN