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Alam, M.
- Study of the Oxidation of Salicylic Acid by CrO3 (VI)
Abstract Views :176 |
PDF Views:1
Authors
M. Alam
1,
A. Prameela
1
Affiliations
1 Department of Chemistry, Ranchi University, Ranchi, Jharkhand, IN
1 Department of Chemistry, Ranchi University, Ranchi, Jharkhand, IN
Source
Asian Journal of Research in Chemistry, Vol 9, No 1 (2016), Pagination: 1-5Abstract
Oxidation of Salicylic acid (in solvent t-butyl alcohol) was carried out by chromium trioxide, i.e. Cr (VI) in solvent t-butyl alcohol and using different (substrate:oxidant) molar ratios. Solid product, with oxidized fragments are obtained in the form of chromium complexes. During the process of oxidation, ligands were obtained in the process itself. After purification , the formulae of these complexes were studied and analyzed.Keywords
Salicylic Acid, TBC.
- Electroorganic Synthesis of Copper and Zinc Complexes with Novel Ligand Oxalic Acid
Abstract Views :64 |
PDF Views:0
Authors
Affiliations
1 St. Xavier’s College, Department of Chemistry, Ranchi ., IN
2 Redt. Professor of PG Department of Chemistry, Ranchi University, Ranchi., IN
3 Redt. Associate Professor, R.L.S.Y College, Ranchi University, Ranchi., IN
1 St. Xavier’s College, Department of Chemistry, Ranchi ., IN
2 Redt. Professor of PG Department of Chemistry, Ranchi University, Ranchi., IN
3 Redt. Associate Professor, R.L.S.Y College, Ranchi University, Ranchi., IN
Source
Asian Journal of Research in Chemistry, Vol 15, No 4 (2022), Pagination: 265 - 271Abstract
A convenient electroorganic synthesis of divalent metal complexes of empirical formulation [ML2] (M (II) = Cu and Zn; L= oxalic acid) were synthesized at sacrificial metal electrode anode. The metal, as the anode in an undivided cell, is oxidized in the presence of the parent compound of the ligand (HL) in an organic solvent mixture. Gram quantities of complex can be produced in a few hours. Complexes were characterized by elemental analysis, Infrared spectral data, Atomic Absorption spectroscopy and thermal spectral data. The geometrical structure of the synthesized complexes has been identified.Keywords
Oxalic acid, Electroorganic, Atomic absorption spectroscopy, Infrared spectra, Sacrificial electrode.References
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