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Authors
Affiliations
1 Department of Chemistry and Research Centre, Scott Christian College (Autonomous), Nagercoil – 629003, IN
2 Department of Chemistry, N.M. Christian College, Marthandam -629165, IN
3 Dept. of Chemistry and Research Centre, Scott Christian College (Autonomous), Nagercoil- 629003, IN
Source
Asian Journal of Research in Chemistry, Vol 4, No 11 (2011), Pagination: 1765-1768
Abstract
The Zr(IV) and Th(IV)-di-α-formylmethoxy bis(3-pentadecenylphenyl)methane (DFMPM) ethylediamine complex were synthesized and characterized by elemental analysis, conductivity measurements, electronic, infrared, HNMR spectral measurements, metal ion intake and antibacterial studies. The conductance measurements indicate that all the complexes are non-electrolytes. The infrared spectra indicate the coordination of imino nitrogen, M-N and M-O bonds. UV-visible spectra could not provide structural details of these complexes. HNMR data are consistent with IR spectral data. The results indicate that both Zr(IV) and Th(IV) ions are octacoordinated and have moderate antibacterial activity. The metal ion intake indicates the ligand can be used for the extraction of these metals from water.
Keywords
Cardanol, Formaldehyde, Epichlorohydrin, Ethylendiamine Schiff Base.
