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Shukla, Deepika
- Dissociation/Association Behaviour of Alkaline Earth Metal Laurates at Different Temperatures
Abstract Views :163 |
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Authors
Affiliations
1 Department of Chemistry, D.A.V. (P.G.) College, Muzaffarnagar (U.P.), IN
2 Central Building Research Institute, CBRI (A Constitutent Establishment of CSIR), Ministry of Science and Technology (Government of India), Roorkee (Uttarakhand), IN
1 Department of Chemistry, D.A.V. (P.G.) College, Muzaffarnagar (U.P.), IN
2 Central Building Research Institute, CBRI (A Constitutent Establishment of CSIR), Ministry of Science and Technology (Government of India), Roorkee (Uttarakhand), IN
Source
The Asian Journal of Experimental Chemistry, Vol 4, No 1-2 (2009), Pagination: 18-22Abstract
The specific conductance, k (mS cm-1) of alkaline earth metal (Mg/Ca/Sr/Ba) laurates in mixed solvent (50% methanol +50% chloroform) has been measured (30-50oC) in order to look into the dissociation / association behaviour of these surfactant systems. The data for critical micelle concentration (c.m.c) help characterising their micellar behaviour. The significant parameters viz. degree of dissociation (α), dissociation constant(KD) and limiting equivalent conductance at infinite dilution (μo) have been deduced for pre-micellar region (dilute range).Thermodynamic parameters viz., enthalpy, free energy and entropy changes for both dissociation and association processes have also been computed.Keywords
Metal Laurates, Conductance, Dissociation, Association, Critical Micelle Concentration (C.M.C), Thermodynamic Parameters.- Density, Apparent Molar Volume and Expansibility Behaviour of Alkaline Earth Metal Laurates in Non-Aqueous Medium at Different Temperatures
Abstract Views :298 |
PDF Views:1
Authors
Affiliations
1 Department of Chemistry, D.A.V. (P.G.) College, Muzaffarnagar (U.P.), IN
2 Central Building Research Institute, CBRI (A Constitutent Establishment of CSIR), Ministry of Science and Technology (Government of India), Roorkee (Uttarakhand), IN
1 Department of Chemistry, D.A.V. (P.G.) College, Muzaffarnagar (U.P.), IN
2 Central Building Research Institute, CBRI (A Constitutent Establishment of CSIR), Ministry of Science and Technology (Government of India), Roorkee (Uttarakhand), IN
Source
The Asian Journal of Experimental Chemistry, Vol 4, No 1-2 (2009), Pagination: 37-42Abstract
The density measurement, ρ (gcm-3) for alkaline earth metal (Mg/Ca/Sr/Ba) laurates in non-aqueous medium (50% methanol +50% chloroform) at different temperatures (30-50oC) has been used to evaluate various significant parameters viz. apparent molar volume (Φv) and expansibility (E0surf) to explore their solution behaviour. The critical micclle concentration (c.m.c.) as ascertained from ρ-C plots, is found to decrease with increasing temperature and vary with different metals as Mg>Ca>Sr>Ba. Density for these solutions increases with increasing surfactant concentration and decreasing temperature. Partial molar volume (Φov) and experimental limiting slope (Sv) as obtained from Masson's equation provide information on solute-solvent and solute-solute interactions, respectively. Apparent molar volume (Φv) is found to increase with increasing concentration and increasing temperature.Keywords
Alkaline Earth Metal Laurates, Critical Micelle Concentration (c.m.c), Density (ρ), Apparent Molar Volume (Φv), Partial Molar Volume (Φov), Expansibility.- Density Measurement of Alkali and Alkaline Earth Metal Myristates in Non-Aqueous Medium (30°-50°C)
Abstract Views :314 |
PDF Views:1
Authors
Affiliations
1 Department of Chemistry, D.A.V. (P.G.) College, Muzaffarnagar (U.P.), IN
1 Department of Chemistry, D.A.V. (P.G.) College, Muzaffarnagar (U.P.), IN
Source
The Asian Journal of Experimental Chemistry, Vol 4, No 1-2 (2009), Pagination: 57-63Abstract
The present investigation deals with density measurement of alkali (Li, Na, K) and alkaline earth metal (Mg, Ca, Sr, Ba) myristates in 50% methanol-50% chloroform (V/V) solvent-mixture at 30°-50°C. The data have been used to determine critical micelle concentration, cmc, and compute other significant parameters viz. apparent (Φv) and partial (φ°v) molar volumes and partial molar expansibility, E°surfactant. The decreasing cmc with the increase in temperature is in agreement with the result obtained from specific conductance measurements. The variation of cmc with alkali and alkaline earth metals also follows the same order as was found in the study on conductance measurements.Keywords
Critical Micelle Concentration (c.m.c.), Density, Molar Volume and Expansibility.- A Comparative Study of Dissociation/Association Facets of Alkali and Alkaline Earth Metal Myristates
Abstract Views :294 |
PDF Views:1
Authors
Affiliations
1 Department of Chemistry, D.A.V. (P.G.) College, Muzaffarnagar (U.P.), IN
1 Department of Chemistry, D.A.V. (P.G.) College, Muzaffarnagar (U.P.), IN