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Bhojak, N.
- Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Ni(II) Complexes with Amide Ligands
Abstract Views :487 |
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Authors
Neha Yadav
1,
N. Bhojak
2
Affiliations
1 Faculty of Science and Technology, Singhania University
2 GCRC, P.G. Department of Chemistry, Govt. Dungar College (A-Grade), University of Bikaner, Bikaner – 334003
1 Faculty of Science and Technology, Singhania University
2 GCRC, P.G. Department of Chemistry, Govt. Dungar College (A-Grade), University of Bikaner, Bikaner – 334003
Source
International Journal of Advanced Biotechnology Research, Vol 3, No 1 (2013), Pagination: 29-34Abstract
The Present research work describes the synthesis, spectral and antibacterial studies on the complexes of few complexes of Nickel(II) with amide group containing ligands. Synthesis of complexes has been carried out by conventional method as well as by microwave method. The complexes have been characterized on the basis of elemental analysis, infrared, electronic spectra and magnetic susceptibility studies. The microwave method of synthesis of complexes have been found easier, convenient and ecofriendly.Keywords
Nickel(II), Microwave, Amide Ligands
References
- Jarvis AR and Bulloch JH, [1992] The effect of nickel content on the environmental assisted cracking (EAC) behaviour of low alloy steels in sour environments—A review. International Journal of Pressure Vessels and Piping 49(3):271-307.
- David BA and Roche A, [1983] Design of metal chelates with biological activity. 3. Nickel(II) complexes of alkyl and amino hydroxamic acid. Inorganic Chemistry 22(15): 2199-2202.
- Chohan ZH and Sherazi SKA, [1997] Biological Role of Cobalt(II), Copper(II) and Nickel(II) Metal Ions on the Antibacterial Properties of Some Nicotinoyl- Hydrazine Derived Compounds. Metal Based Drugs 4(2); 69-74.
- Riordon CG and Ragsdale SW, [1996] The role of nickel in acetyl-CoA synthesis by the bifunctional enzyme Co dehydrogenase/acetyl- CoA synthase: enzymology and model chemistry. Journal of Biological Inorganic Chemistry 1(6): 489-493.
- Tounsi N, Dupont L, Guillon E, and AplinCourt M, [2007] Interaction of copper(II) and nickel(II) with a bis-amide ligand functionalized with pyridine moieties: Thermodynamic and spectroscopic studies in aqueous solution. Inorganica Chimica Acta 360(8): 2598-2608.
- Singh BK, Bhojak N, and Prakash A, [2012] Unsymmetrical Schiff base Functionalized as Monobasic Tridentate Ligand on Complexation with some transition metal ions. E-Journal of Chemistry 9(2): 532-544.
- Synthesis Spectral and Antibacterial Studies on Few Semicarbazones of Benzaldehyde Derivatives
Abstract Views :573 |
PDF Views:0
Authors
Affiliations
1 Singhania University
2 GCRC, Govt Dungar College (A-Grade), MGS University Bikaner- 334003, IN
1 Singhania University
2 GCRC, Govt Dungar College (A-Grade), MGS University Bikaner- 334003, IN
Source
International Journals of Biotechnology and Biochemistry, Vol 9, No 1 (2013), Pagination: 45-48Abstract
The present paper describe synthesis, spectral and antibacterial investigations on tweleve semicarbazones derived from 2-Hydroxybenzaldehyde, 3-Hydroxybenzaldehyde, 4-Hydroxybenzaldehyde, 2-Chlorobenzaldehyde, 3-Chlorobenzaldehyde, 4-Chlorobenzaldehyde, 2-Nitrobenzaldehyde, 3-Nitrobenzaldehyde, 4-Nitrobenzaldehyde. 2-Methoxybenzaldehyde, 3-Methoxybenzaldehyde, 4-Methoxybenzaldehyde. The synthesized complexes have been characterized on the basis of IR, NMR and elemental analysis after checking purity. Antibacterial studies have been studied on staphylococcus aureus and order of antibacterial activity was found in the following order CBSC > MBSC ≈HBSC > NBSC. The effect of structure and position of secondary group on antibacterial activity have also been investigated and in general it has been found that ortho effect reduces the antibacterial activity.Keywords
Semicarbazones, Antimicrobial Activity, Ortho EffectReferences
- Garg, B.S., and Jain, V.K., 1987, “Applications of semicarbazones a Review”, Microchemical J, 4 , pp, 112.
- Afrasiabi, Z., Sinn, E., Lin, W., Ma, Y., Campana, C. and Padhye, S., 2005, “Nickel (II) complexes of naphthaquinone thiosemicarbazone and semicarbazone: Synthesis, structure, spectroscopy, and biological activity”,J.Inorg. Biochem, 99, pp.1526.
- Kasuga, N.C., Sekino, K., Ishikawa, M., Honda, A., Yokoyama, M., Nakano, S., Shimada, N., Koumo, C. and Nomiya, K., 2003, “Synthesis, structural characterization and antimicrobial activities of 12 zinc(II) complexes with four thiosemicarbazone and two semicarbazone ligands” ,J. Inorg. Biochem, 96, pp.298.
- Sriram, D., Yogeeswari, P. and Thirumurugan, R. S., 2004, “Antituberculous activity of some aryl semicarbazone derivatives” , Bioorg. Med. Chem.Lett, 14, pp.3923.
- Noblia, P., Vieites, M., Parajon-Costa, B.S., Baran, E.J., Cerecetto, H., Draper, P., Gonzalez, M., Piro, O.E., Castellano, E.E., Azqueta, A., Lopez, D.C., MongeVega, A. and Gambino, D., 2005, “Vanadium(V) complexes with salicylaldehyde semicarbazone derivatives bearing in vitro anti-tumor activity toward kidney tumor cells (TK-10): crystal structure of [VVO2(5-bromosalicylaldehyde semicarbazone)]” , J. Inorg. Biochem, 99, pp.443.
- Bhandari, H. S. , Gudesaria, D. D., Purohit, S. and Bhojak, N., 2010, “Thermodynamical Behavior of Doped Sm (III) Ions in Saturated Alcoholic Solutions of Amide Group Containing Ligands Derived from Heterocyclic Amines” , Int. J. Chem. Sci., 8(1), pp. 393.
- Mulliez, E., Fontecave, M., 1999, Coor. Chem. Rev., “Ribonucleotide reductases: metal and free radical interplay”, 185, pp.775.