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Wang, Jianxu
- Effect of H2O2/Fe2+ Concentration Ratios on Fenton Oxidation of Reactive Red 6B with On-Line Detective Technology
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Affiliations
1 Chemical Engineering and Pharmaceutics School, Henan University of Science and Technology, Luoyang 471023, CN
2 College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, CN
1 Chemical Engineering and Pharmaceutics School, Henan University of Science and Technology, Luoyang 471023, CN
2 College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, CN
Source
Nature Environment and Pollution Technology, Vol 14, No 1 (2015), Pagination: 71-76Abstract
The degradation of Reactive Red 6B (RR6B) wastewater was treated by Fenton oxidation using on-line spectrophotometric monitoring technology. The ratio of peroxide hydroxide concentration and ferrous ion dosage (HF) was investigated. Dyeing degradation process followed first order kinetics and Behnajady - Modirshahla-Ghanbery kinetics because of above 0.98 R2. Fenton process transient reaction rate and instant hydroxyl radical concentration was calculated. The optimum HF was 143 with 98% dye removal, 0.05mol/(L·s) instant transient reaction rate and 2.4×10-11mol/L initial hydroxyl radical concentration.Keywords
Fenton Process, Hydroxyl Radical, Kinetics, Wastewater Treatment.- Kinetics Study of Fenton Degradation of Acid Yellow G by Online Spectrometry Technology
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Authors
Affiliations
1 Chemical Engineering and Pharmaceutics School, Henan University of Science and Technology, Luoyang 471023, CN
2 College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, CN
1 Chemical Engineering and Pharmaceutics School, Henan University of Science and Technology, Luoyang 471023, CN
2 College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, CN
Source
Nature Environment and Pollution Technology, Vol 15, No 3 (2016), Pagination: 991-996Abstract
The kinetics of Fenton degradation of azo dye Acid Yellow G by online spectrometry technology was studied in this research. The main influential parameters of Fenton process such as FeSO4 dosage, H2O2 dosage, reaction temperature and pH were investigated and the optimum conditions were 20mg/L FeSO4, 50mg/L H2O2, pH=3 and 38°C. Degradation kinetics analyses of acid yellow G were carried out for superior interpretation of Fenton process and the result indicated that the Behnajady-Modirshahla-Ghanbery (B-M-G) model is more applicable than the first or second order kinetics.Keywords
Fenton Process, Acid Yellow G, Degradation, Online Spectrometry, BMG Model.References
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