Abstract Views :183 |
PDF Views:3
Authors
Affiliations
1 Department of Chemistry, University of Guilan, P.O. Box 1914, Rasht, IR
2 Department of Chemistry, Research Centre Medicinal Plants, Islamic Azad University, Ardabil, IR
3 Department of Electrical and Computer Engineering, University of Tehran, Tehran, IR
Source
Oriental Journal of Computer Science and Technology, Vol 2, No 2 (2009), Pagination: 123-125
Abstract
Reaction of some diamines and ketones in the presence of catalytic amount of dodecylbenzene sulfonic acid leads to the formation of 2,3–dihydro -1H-1,5-benzodiazepines in good yields. It seems that dodecylbenzene sulfonic acid has two roles: first it acts as a surfactant to dissolve starting materials in water, and second it acts as an acidic catalyst to activate carbonyl groups.
Keywords
Benzodiazepine, Dodecylbenzene Sulfonic Acid, Imine–Enamine Cyclization.
Full Text