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Jabur, Hasan Sabeeh
- Synthesis Characterization and Study of Some Electrical Properties of Compound of Octa phenyl porphyrazin Cobalt (III) complexes
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Authors
Affiliations
1 Chemistry Department College of Science, University of Al-Muthana, Al-Muthana, IQ
1 Chemistry Department College of Science, University of Al-Muthana, Al-Muthana, IQ
Source
Research Journal of Pharmacy and Technology, Vol 12, No 1 (2019), Pagination: 357-360Abstract
The present study the preparation of complexes octaphenalporphyrazinCobalt (III), the prepared compounds are characterized by elemental analysis, infrared, uv-visible, and 1H-NMR. The elemental analysis results showed a good agreement with the calculated results.The IR-spectra show a strong band at the range (2235-2240cm-1 ). which are attributed to the stretching vibrations of the (C≡N) band and hidden in the complexes.The UV-Visible spectra are characterized by the appearance of the two main absorption bands. The first at the range (600-675) nm which is called Q-band and the second at the range (305-350) nm which is called B or sort band. The 1H-NMR spectra data of all prepared compounds are similar, in general, and consist of aromatic protons signals within the range (735-793) ppm which is attributed to the meta, para and Ortho protons. Electrical conductivity of the polymer was measured by using the iodine doping .lt was found that the electrical conductivity increased up to (10-4 ohm-1. Cm-1).Keywords
Octa Phenyl Porphyrazincobalt, Electrical Conductivity, Iodine Doping.
References
- R. P. Linstead and M. Whalley, J. Chem. Soc. 4839, (1952).
- S. L. J Miche, S.Baum, A.G.M. Barrett and B.M. Hoffman, "Progress in Inorganic Chemistry", Wiley:New York (2001).
- F. H. Moser and A.L Thomas "Phthalocyanine compounds "Reinhold publishing corobration, New York,(1963).
- J.Simon and J. J. Andre," Molecular Semiconductors", Springer-Verlag, Berlin, (1985).
- R. P. Linstead, J.Chem.Soc.,1016, (1934).
- G. T. Byrne, R. P.Linstead and A.W.Lowe,J.Chem. Soc.,1017, (1934)
- C. C. Leznoff and A. B. P. Lever," Phthalocyanines: Properties and Applications", VCH Publishers, Amsterdam, (1996); Vol.4.
- Z. Musil, P. Zimcik, M.Miletin, K. Kopecky, P. Petrik and J. Lenco, J. Photochemistry and Photobiology A:Chemistry, (2007); 186: 316
- H. J. Kim, Ph. D. thesis, University of North Carolina Stare, USA, (2005).
- M. Gyer, etal., J. Synth. Org Chem.,1139, (1996) .
- K. Kasugaan and M. Tsutsui., Coord. Chem. Rev., 32,67, (1980).
- M. Goyer, F. Plenzig, J. Rauschnable, M. Hannak, B. Delrey, A. Sastre and T. Torres, Synthesis, 1139, (1996).
- M. P. Donzello, C. Ercolani, P. A. Stuzhin Coordination Chemistery Reviews, (2006), 250: 1530.
- M. P. Donzello et al., Inorg. Chem., (2004); 43 (26): 8626.
- R. M. Silverstein and F. X-Webster, "Spectroscopic Identification of Organic Compounds", 6th Ed, John Wiley and Sons, Inc., New York (1996).
- R. J. Reynolds and K. Aldous, Atomic Absorption spectroscopy, charls Griffin, London, (1970).
- Synthesis Characterization and Study of some electrical properties of compound of Octaphenylporphyrazin Cobalt (III) Complexes
Abstract Views :166 |
PDF Views:0
Authors
Affiliations
1 Chemistry Department College of Science. University of Al-Muthana. Al-Muthana, IQ
1 Chemistry Department College of Science. University of Al-Muthana. Al-Muthana, IQ
Source
Research Journal of Pharmacy and Technology, Vol 12, No 2 (2019), Pagination: 495-498Abstract
The present study the preparation of complexes octaphenalporphyrazin Cobalt (III), the prepared compounds are characterized by elemental analysis, infrared, uv-visible, and 1H-NMR. The elemental analysis results showed a good agreement with the calculated results. The IR-spectra show a strong band at the range (2235-2240cm-1 ). which are attributed to the stretching vibrations of the (C≡N) band and hidden in the complexes.The UV-Visible spectra are characterized by the appearance of the two main absorption bands. The first at the range (600-675)nm which is called Q-band and the second at the range (305-350)nm which is called B or sort band. The 1H-NMR spectra data of all prepared compounds are similar, in general, and consist of aromatic protons signals within the range (735-793) ppm which is attributed to the meta, para and Ortho protons. Electrical conductivity of the polymer was measured by using the iodine doping. lt was found that the electrical conductivity increased up to (10-4 ohm-1. Cm-1).Keywords
Octa Phenyl Porphyrazin Cobalt, Electrical Conductivity, Iodine Doping.References
- R. P. Linstead and M. Whalley, J. Chem. Soc. 4839, (1952).
- S. L. J Michel, S.Baum, A.G.M. Barrett and B.M. Hoffman, " Progress in Inorganic Chemistry", Wiley: New York(2001).
- F. H. Moser and A.L Thomas "Phthalocyanine compounds "Reinholdpublishingcorobration, New York, (1963).
- J.Simon and J. J. Andre," Molecular Semiconductors", Springer-Verlag, Berlin,(1985).
- R.P. Linstead, J.Chem.Soc., 1016, (1934).
- G.T.Byrne, R.P.Linstead and A.W.Lowe, J.Chem. Soc.,1017, (1934)
- C. C. Leznoff and A. B. P. Lever," Phthalocyanines: Properties and Applications", VCH Publishers, Amsterdam, (1996); Vol.4.
- Z. Musil, P. Zimcik, M.Miletin, K. Kopecky, P. Petrik and J. Lenco, J. Photochemistry and Photobiology A:Chemistry, (2007); 186: 316
- H. J. Kim, Ph. D. thesis, University of North Carolina Stare, USA, (2005).
- M. Gyer, etal., J. Synth. Org Chem.,1139, (1996).
- K. Kasugaan and M. Tsutsui., Coord. Chem. Rev., 32,67, (1980).
- M. Goyer, F. Plenzig, J. Rauschnable, M. Hannak, B. Delrey, A. Sastre and T. Torres, Synthesis, 1139, (1996).
- M. P. Donzello, C. Ercolani, P. A.StuzhinCoordination Chemistery Reviews, (2006); 250: 1530.
- M. P.Donzello et al. ,Inorg. Chem., (2004); 43(26): 8626.
- R. M. Silverstein and F. X-Webster, "Spectroscopic Identification of Organic Compounds", 6thEd, John Wiley and Sons, Inc. ,New York (1996).
- R. J. Reynolds and K. Aldous, Atomic Absorption spectroscopy, charls Griffin, London, (1970).