Journal of Pure and Applied Ultrasonics

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Ultrasonic Speed and Related Acoustical and Thermodynamic Activation Parameters of (2E, 6eE-bis (4-Hydroxybenzylidene)-4-Methylcyclohexanone in 1, 4-Dioxane, Ethanol and Tetrahydrofuran Solutions at 298, 303, 308, and 313K


Affiliations
1 Department of Chemistry, Saurashtra University, Rajkot-360 005, Gujarat, India
 

The density, viscosity and ultrasonic speed of pure solvents: 1,4-dioxane (DO), tetrahydrofuran (THF), ethanol (EtOH) and (2E, 6E)-bis (4-hydroxy benzylidene)-4-methylcyclohexanone (MBHBC) solutions of different concentrations were investigated at four different temperatures: 298, 303, 308, and 313 K to understand the effect of solvents and temperature on molecular interactions. Various acoustical and thermodynamic parameters such as acoustical impedance, adiabatic compressibility, internal pressure, free volume, inter molecular free path length, van der Waals constant, viscous relaxation time, classical absorption coefficient, Rao`s molar sound function and solvation number of MBHBC solutions were determined using density, viscosity and ultrasonic velocity data and correlated with concentration at the different temperature. Thermodynamic activation parameters such as Gibbs free energy, enthalpy and entropy were derived using viscous relaxation time data. Very good to excellent correlation between a given parameter with concentration and temperature is observed. Derived parameters supported existence of strong molecular interactions in MBHBC solutions. It is observed that MBHBC has structure forming tendency in DO, THF and EtOH systems.

Keywords

Density, Viscosity, Ultrasonic Speed, Solvation Number, Molecular Interactions.
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  • Pei J.,Yao H., Wang H., Shan D., Jiang Y., Ma L.and Yu X.,Effect of ultrasonic and ozone pre-treatments on pharmaceutical waste activated sludge's solubilisation, reduction, anaerobic biodegradability and acute biological toxicity. Bioresource Technol. 192(2015) 418-423.

  • Nieman D.C., Shanely R.A., Zwetsloot K.A., Meaney M.P.and Farris G.E.,Ultrasonic assessment of exercise-induced change in skeletal muscle glycogen content. BMC Sports Sci. Med. Rehabil.2015 Apr 18; 7:9. doi: 10.1186/ s13102-015-0003-z. eCollection 2015.

  • Vieira da Silva B., Barreira J.C.M.and Oliveira M.B.P.P.,Natural phytochemicals and probiotics as bioactive ingredients for functional foods: extraction, biochemistry and protected-delivery technologies. Trends Food Sci. Technol. 50(2016) 144-158.

  • Slak B., Daabous A., Bednarz W., Strumban E.and Maev R.G.,Assessment of gingival thickness using an ultrasonic dental system. Annals of Anatomy-Anatomischer Anzeiger 199(2015) 98-103.

  • Yusuf N.S.M., Babgi B., Alghamdi Y., Aksu M., Madhavan J.and Ashok Kumar M.,Physical and chemical effects of acoustic cavitation in selected ultrasonic cleaning applications. Ultrason. Sonochem. 29 (2016) 568-576.

  • Chemat F., Rombaut N., Meullemiestre A., Turk M., Perino S., Fabiano-Tixier A.S.and Abert-Vian M., Review of green food processing techniques: Preservation, transformation, and extraction. Innovative Food Sci. Emerging Technol. 41(2017) 357-377.

  • Gahlyan S., Rani M.and Maken S.,Ultrasonic speeds, viscosities, refractive indices and FT-IR spectroscopic studies of an oxygenate with aliphatic and aromatic hydrocarbons at 298.15 K and 308.15 K. J. Mol. Liq. 219(2016) 1107-1123.

  • BaÕlar M., KlllçllM., Toker O.S., Sa—dlç O.and Arici M.,Ultrasonic vacuum drying technique as a novel process for shortening the drying period for beef and chicken meats. Innovative Food Sci. Emerging Technol. 26(2014) 182-190.

  • Awad T.S., Moharram H.A., Shaltout O.E., Asker D. and Youssef M.M.,Applications of ultrasound in analysis, processing and quality control of food?: A review. Food Res. Int. 48(2012) 410-427.

  • Cardoso M., Martinelli C.S.M., Carvalho C.A.T., Borges A.B.and Torres C.R.G.,Ultrasonic activation of internal bleaching agents. Int. Endodontic J. 46(2013) 40-46.

  • Maddikeri G.L., Pandit A.B.and Gogate P.R., Ultrasound assisted interesterification of waste cooking oil and methyl acetate for biodiesel and triacetin production. Fuel Processing Technol. 116(2013) 241-249.

  • Bulasara V.K., Uppaluri R.and Purkait M.K.,Effect of ultrasound on the performance of nickel hydrazine electroless plating baths. Mater. Manuf. Processes 27 (2012) 201-206.

  • Sancheti S.V.and Gogate P.R.,A review of engineering aspects of intensification of chemical synthesis using ultrasound. Ultrason. Sonochem. 36(2017) 527-543.

  • Patel R.V., Mistry B.M., Shinde S.K., Syed R., Singh V.and Shin H.S.,Therapeutic potential of quercetin as a cardiovascular agent. Eur. J. Med. Chem. 155(2018) 889-904.

  • McIntosh K., Smith A., Young L., Leitch M., Tiwari A., Reddy C.,O'Neil G., Liberatore M., Chandler M. and Baki G.,Alkenones as a promising green alternative for waxes in cosmetics and personal care products. Cosmetics 5(2018) 34; https://doi.org/10.3390/ cosmetics5020034.

  • Vogel A.I., Tatchell A.R., Furnis B.S., Hannaford A.J. and Smith P.W.G.,Vogel's Textbook of Practical Organic Chemistry, 5thedn. Addison Wesley Longman, London (1998) 395.

  • Sankhavara D.B., Chopda J.V., Patel J.P.and Parsania P.H.,Synthesis, spectral and thermal study of (2E, 6E)-2,6-bis(4-hydroxybenzylidene)-4-R-cyclohexanone. World Scientific News 12(2019) 141-160.

  • Koneti A.K.and Chintalapati S.,Speeds of sound and excess molar volume for binary mixture of 1 , 4-dioxane with 1-heptanol at five temperatures. Adv. Chem.(2014) 1-7, doi.org/10.1155/2014/343012.

  • Dhaduk B.B., Patel C.B.and Parsania P.H.,Ultrasonic speed and related thermo-acoustical parameters of solutions of 1,10-bis(3-methyl-4-ethoxyacetylphenoxy) cyclohexane at four different temperatures. J. Sol. Chem. 44(2015) 1976-1996

  • Al-Omair N.A., Das A.D., Snoussi L., Sinha B., Pradhan R., Acharjee K., Saoudi K.and Ouerfelli N., A partial derivatives approach for estimation of the viscosity Arrhenius temperature in N, N dimethyl formamide+1,4-dioxane binary fluid mixtures at temperatures from 298.15 K to 318.15 K. Phys. Chem. Liq. 54(2016) 615-631.

  • Sirbu F., Ion A.C., Capra L.and Ion I.,A thermodynamics study on the tetrahydrofuran effect in exfoliated graphite nanoplatelets and activated carbon mixtures at temperatures between 293.15 and 308.15K. Adv. Mater. Sci. Engg.(2018) 1-13.

  • Nain A.K.,Ultrasonic and viscometric studies of molecular interactions in binary mixtures of tetrahydrofuran with some aromatic hydrocarbons at temperatures from 288.15 to 318.15 K. Phys. and Chem. Liq. 45(2007) 371-388.

  • Sinha A.and Roy M.N.,Densities, viscosities, and sound speeds of some acetate salts in binary mixtures of tetrahydrofuran and methanol at (303.15, 313.15, and 323.15) K. J. Chem. Engg. Data 51(2006) 1415-1423.

  • Dhaduk B.B., Patel C.B.and Parsania P.H.,Molecular interactions in 1,4-dioxane, tetrahydrofuran, and ethyl acetate solutions of 1,1'-bis(4-isopropyloxyacetyl-phenoxy) cyclohexane on reological, density, and acoustic behavior. Russ. J. Phys. Chem. 91(2017) 2495-2502.

  • Ali A., Nain A.K.and Kamil M.,Physico-chemical studies of non-aqueous binary liquid mixtures at various temperatures. Thermochimica Acta 274(1996) 209-221.

  • Han C., Xia S., Ma P.and Zeng F.,Densities of ionic liquid [bmim][bf4] + ethanol, + benzene, and + acetonitrile at different temperature and pressure. J. Chem. Engg. Data 54(2009) 2971-2977.

  • Yang C., Sun Y., He Y.and Ma P.,Volumetric properties and viscosities of binary mixtures of n,n-dimethylformamide with methanol and ethanol in the temperature range (293.15 to 333.15) K. J. Chem. Engg. Data 53(2008) 293-297.

  • Zafarani-Moattar M.T.and Tohidifar N.,Vapor-liquid equilibria, density, speed of sound, and viscosity for the system poly (ethylene glycol) 400 + ethanol at different temperatures. J. Chem. Engg. Data 53(2008) 785-793.

  • Suryanarayana C.V.and Kuppuswamy J.,Role of internal pressure in the chemistry of electrolyte solutions. Acoust. Soc. 9(1981) 4-8.

  • Jacobson B., Anderson W.A.and Arnold J.T.,A proton magnetic resonance study of the hydration of deoxyribonucleic acid, Nature 173(1954) 772-773.

  • Vigoureux P.,Ultrasonic, Chapman and Hall, London, (1952) 112.

  • Subrahmanyam T.V.S.and Sarma A.V.,Ultrasonic absorption studies in binary mixtures of ethanolamine. Acustica 79(1993) 88-92.

  • Bagchi S., Nema S.and Singh R.,Ultrsonic and viscometric investigation of ISRO polyol in various solvents and its compatibility with polypropylene. Euro. Polym. J. 22(1986) 851-857.


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  • Ultrasonic Speed and Related Acoustical and Thermodynamic Activation Parameters of (2E, 6eE-bis (4-Hydroxybenzylidene)-4-Methylcyclohexanone in 1, 4-Dioxane, Ethanol and Tetrahydrofuran Solutions at 298, 303, 308, and 313K

Abstract Views: 203  |  PDF Views: 1

Authors

J.V. Chopda
Department of Chemistry, Saurashtra University, Rajkot-360 005, Gujarat, India
D. B. Sankhavara
Department of Chemistry, Saurashtra University, Rajkot-360 005, Gujarat, India
J. P. Patel
Department of Chemistry, Saurashtra University, Rajkot-360 005, Gujarat, India
P. H. Parsania
Department of Chemistry, Saurashtra University, Rajkot-360 005, Gujarat, India

Abstract


The density, viscosity and ultrasonic speed of pure solvents: 1,4-dioxane (DO), tetrahydrofuran (THF), ethanol (EtOH) and (2E, 6E)-bis (4-hydroxy benzylidene)-4-methylcyclohexanone (MBHBC) solutions of different concentrations were investigated at four different temperatures: 298, 303, 308, and 313 K to understand the effect of solvents and temperature on molecular interactions. Various acoustical and thermodynamic parameters such as acoustical impedance, adiabatic compressibility, internal pressure, free volume, inter molecular free path length, van der Waals constant, viscous relaxation time, classical absorption coefficient, Rao`s molar sound function and solvation number of MBHBC solutions were determined using density, viscosity and ultrasonic velocity data and correlated with concentration at the different temperature. Thermodynamic activation parameters such as Gibbs free energy, enthalpy and entropy were derived using viscous relaxation time data. Very good to excellent correlation between a given parameter with concentration and temperature is observed. Derived parameters supported existence of strong molecular interactions in MBHBC solutions. It is observed that MBHBC has structure forming tendency in DO, THF and EtOH systems.

Keywords


Density, Viscosity, Ultrasonic Speed, Solvation Number, Molecular Interactions.

References