Open Access Open Access  Restricted Access Subscription Access

Study of Excess Thermoacoustical Parameters of THF and Strontium Hydroxide


Affiliations
1 Department of Physics, Lokmanya Tilak College, Wani-445304, India
2 Department of Electronics, Anand Niketan College, Warora-442914, India
3 Department of Physics, Arts, Commerce & Science College, Maregaon-445303, India
4 Department of Physics, RTM Nagpur University, Nagpur-440 033, India
 

The ultrasonic velocity density and viscosity of binary liquid mixture of tetrahydrofuran and strontium hydroxide (solvent) have been measured over the entire range of compositions at the temperatures 298K, 303K, 308K at fixed and frequency 7 MHz. The observed basic experimental data have been utilized to evaluate some of the derived thermoacoustic parameters such as adiabatic compressibility, molar volume relaxation time. The behavior of these derived parameters and their excess values of, adiabatic compressibility, molar volume relaxation time were evaluated with composition of the mixture and have been discussed in terms of nature and strength of molecular interactions between the constituents. Broad classification study also helps to understand the molecular interaction types.

Keywords

Uracil, Thermoacoustic Parameters, Ultrasonic Absorption, IDR.
User
Notifications
Font Size

  • Ali A. and Nair A.K., Ultrasonic study of molecular interaction in binary liquid mixtures at 30°C, Pramana. 58 (2002) 695-701.
  • Nayeema S.K. and Krishna Rao D., Ultrasonic Investigations of Molecular Interaction in binary mixtures of benzyl benzoate with isomers of butanol. Int. J.P. Res. Rev. 3 (2014) 65-78.
  • Ali A. and Nair A.K., Ultrasonic study of molecular interaction in N-N dimethyl foramide + ethanol binary liquid mixtures at various temperatures, Acoust. Lett. 19 (1996) 181-187.
  • Sumathi T. and Varalakshmi M., Ultrasonic velocity, density, viscosity measurement of methionine in aqueous electrolytic solution at 303 K. Ras. J. Chem. 3 (2010) 550-555.
  • Bhandakkar V.D., Tabhane V.A. and Ghosh S., Ultrasonic study of molecular interactions in binary liquid mixtures: acrolien & cinnamaldehyde in methanol, cyclohexane & p-dioxane. Indian J. Pure Appl. Phys. 41 (2003) 849-854.
  • Bhandakkar V.D. and Rode S.S., Acoustical studies on molecular interactions in binary liquid mixtures at 303K, Adv. Appl. Sci. Res. 3(5) (2012) 3223-3229.
  • Bhandakkar V.D., Bhat V.R., Chimankar O.P. and Asole A.W., Thermoacoustical study of tetrahydrofuran with ethanol using ultrasonic technique at 323K, Adv. Appl. Sci. Res. 5(2) (2014) 80-85.
  • Bhandakkar V.D., Rode S.S. and Maddi P.A. Thermoacoustical and nonlinear molecular interaction studies in binary liquid mixtures at 303K, Arch. Appl. Sci. Res. 4(6) (2012) 2546-2551.
  • Bhandakkar V.D, Bedare G.R., Muley V.D. and Suryavanshi B.M., Molecular interactions of Acrylonitrile and methyl methacrylate in methanol, cyclohexane and p-dioxane. Adv. Appl. Sci. Res. 2(4) (2011) 380-386.
  • Srinivasulu V. and Naidu P.R., Ultrasonic behaviour of liquid mixtures of n-hexane with 1-alknaols at 303.15K, J. Pure and Appl. Ultrason., 17 (1995) 14-28.
  • Jamankar G.M. and Deshpande M.S., Ultrasonic investigations of molecular interaction in binary mixtures of ellagic acid with acetone, J. Pure Appl. Ultrason. 40 (2018) 12-15.
  • Bhandakkar V.D., Chimankar O.P. and Pawar N.R. Ultrasonic study of molecular interactions in some bio-liquids. J. Chem. Pharm. Res. 2 (2010) 873-877.
  • Bhandakkar V.D., An accurate representation of molecular clusters in liquid mixtures using Khasare's equation of state. Adv. Appl. Sci. Res. J. 2 (2011) 198-207.
  • Bhandakkar V.D., Chimankar O.P. and Pawar N.R., Thermo dynamic behaviour of methyl methacrylate in methanol, p-dioxane and cyclohexane, Indian J. Pure Appl. Phy. 49 (2011) 550-556.
  • Prasad N. and Rajendra H., Excess free volume and internal pressure of binary solutions of N, Ndimethyl aniline and halomethanes. J. Pure. Appl. Ultrason. 25 (2003) 25.
  • Bageshwar P.D., Chimankar O.P. and Pawar N.R., Ultrasonic characterization of thymine in aqueous solution by non-destructive technique. J. Pure Appl. Ultrason. 38 (2016) 40-42.
  • Rajgopal K. and Chenthilnath S., Excess thermodynamic studies of binary mixtures of 2-methyl-2 propanol with ketones, Indian J. Pure Appl. Phy. 48 (2010) 326-333.
  • Bhandakkar V.D. and Asole A.W., Excess thermo dynamic parameters of binary liquid mixtures at 303K. J. Pure Appl. Indust. Phys. 3 (2013) 80-86.

Abstract Views: 187

PDF Views: 1




  • Study of Excess Thermoacoustical Parameters of THF and Strontium Hydroxide

Abstract Views: 187  |  PDF Views: 1

Authors

V. R. Bhat
Department of Physics, Lokmanya Tilak College, Wani-445304, India
V. D. Bhandakkar
Department of Electronics, Anand Niketan College, Warora-442914, India
N. R. Pawar
Department of Physics, Arts, Commerce & Science College, Maregaon-445303, India
O. P. Chimankar
Department of Physics, RTM Nagpur University, Nagpur-440 033, India

Abstract


The ultrasonic velocity density and viscosity of binary liquid mixture of tetrahydrofuran and strontium hydroxide (solvent) have been measured over the entire range of compositions at the temperatures 298K, 303K, 308K at fixed and frequency 7 MHz. The observed basic experimental data have been utilized to evaluate some of the derived thermoacoustic parameters such as adiabatic compressibility, molar volume relaxation time. The behavior of these derived parameters and their excess values of, adiabatic compressibility, molar volume relaxation time were evaluated with composition of the mixture and have been discussed in terms of nature and strength of molecular interactions between the constituents. Broad classification study also helps to understand the molecular interaction types.

Keywords


Uracil, Thermoacoustic Parameters, Ultrasonic Absorption, IDR.

References