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Solvent Free Synthesis, Characterization and Evaluation of Dimethylaminopropylamine based Double Tailed Amidoamine Cationic Surfactant


Affiliations
1 Department of Chemical Engineering, Institute of Chemical Technology, Mumbai - 400019, India
2 Department of Chemical Engineering, Institute of Chemical Technology, Mumbai - 400019, Maharashtra, India
     

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Lauramidopropyl dimethylamine was quaternised using Lauryl Bromide to synthesize a double chain cationic surfactant. The surfactant was obtained in good yield without the use of any solvent. Amidoamine cationic surfactant chemical structure was analyzed using mass spectroscopic technique. The physicochemical properties of the amidoamine surfactant were calculated from surface tension and conductance measurements giving a critical micelle concentration of 8.04 × 10-3 mM which is quite lower than conventional surfactants. The amidoamine also exhibits a good foaming ability and wettability. The amidoamine cationic surfactant was evaluated for efficacy against different microorganisms and the results show that it has good antimicrobial activity against both Gram positive and Gram negative bacteria.

Keywords

Amidoamine, Critical Micelle Concentration, Quaternization, Surfactant, Synthesis.
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  • K. Holmberg, Novel surfactants: preparation applications and biodegradability, 2nd edn, Surfactant Science Series, CRC Press, pp 276-284, (2003).
  • R. Valivety, I. S. Gill, and E. N. Vulfson, J. Surfactants Deterg., 1, 177 (1998).
  • M. Rafiquee, N. Saxena, S. Khan, and M. Quraishi, Mater. Chem. Phys., 107, 528 (2008).
  • S. P. Sulakhe and S. S. Bhagwat, J. Surfactants Deterg., 16, 487 (2013).
  • S. M. Shaban. I. Aiad, M. M. El-Sukkary, E. Soliman, and M. Y. El-Awady, J. Mol. Liq., 203, 20 (2015).
  • S. Muralidharan and S. V. Iyer, Anti Corros. Method M, 44, 100 (1997).
  • S. M. Shaban, I. Aiad. M. M. El-Sukkary, E. Soliman, and M. Y. El-Awady, Ind. Eng. Chem. Res., 21, 1029 (2015).
  • I. A. Aiad, S. M. Tawfik, S. M. Shaban, A. A. Abd-Elaal, and M. El-Shafie, J. Surfactants Deterg., 17, 391 (2014).
  • I. Aiad, M. M. El-Sukkary, E. Soliman, M. Y. El-Awady, and S. M. Shaban, Ind. Eng. Chem. Res., 20 (5), 3430 (2014).
  • N. A. Negm and A. S. Mohamed, J. Surfactants Deterg., 11(3), 215 (2008).
  • G. McDonnell and A. D. Russell, Clin. Microbiol. Rev., 14(1), 227 (2001).
  • M. Minguet, N. Subirats, and P. Castan. 55th Sepawa Congress and European Detergents Conference Proceedings, 55, 174 (2008).
  • M. Minguet, N. Subirats, P. Castan, and T. Sakai, Int. J. Cosmet. Sci., 32 (4), 246 (2010).
  • M. Yamane, T. Toyo, K. Inoue, T. Sakai, Y. Kaneko, and N. Nishiyama, J. Oleo. Sci., 57 (10), 529 (2008).
  • S. M. Shaban, I. Aiad, H. A. Fetouh, and A. Maher, J. Mol. Liq., 212, 699 (2015).
  • R. Brubaker, H. Muranko, D. Smith, G. Beck, and G. Scovel, J. Occup. Environ. Med. 21(10), 688 (1979).
  • P. T. Erskine, R. Newbold, J. Roper, A. Coker, M. J. Warren, S. P. Wood, and J. B. Cooper, Protein Sci., 8(6), 1250 (1999).
  • M. Young, H.-L. Alakomi, I. Fortune, A. Gorbushina, W. Krumbein, I. Maxwell, C. McCullagh, P. Robertson, M. Saarela and J. Valero, Environ. Geol., 56(3), 631 (2008).
  • G. Cerchiaro, A. M. D. C. Ferreira, A. B. Teixeira, H. M. Magalhaes, A. C. Cunha, V. F. Ferreira, L. S. Santos, M. N. Eberlin, J. M. Skakle and S. M. Wardell, Polyhedron, 25(10), 2055 (2006).
  • M. Rosen. Surfactants and interfacial phenomena, Wiley (2nd end.), New York, 39, pp 82–161 (1989).
  • P. R. Garrett and P. R. Moore, J. Colloid Interface Sci., 159 (1), 214 (1993).
  • J. J. Bikerman, Foams: Theory and Industrial Applications, Reinhold, pp 108-110 (1953).
  • J. Ross and G. D. Miles, J. Am. Oil Chem. Soc., 18(5), 99 (1941).
  • R. S. Powale and S. S. Bhagwat, J. Dispersion Sci. Technol., 27 (8), 1181 (2006).
  • S. Desai and S. S. Bhagwat, J. Surfactants Deterg., 19 (6), 1169 (2016).
  • M. B. Ahire and S. S. Bhagwat, J. Surfactants Deterg., 2017, 1 (2016).
  • K. Holmberg, Handbook of Applied Surface and Colloid Chemistry, 2, Wiley New York, pp 249-286 (2002).
  • Y. Yuan and T. R. Lee, Surface Science Techniques, Springer, pp 3-30 (2013).
  • G. Viscardi, P. Quagliotto, C. Barolo, P. Savarino, E. Barni, and E. Fisicaro, J. Org. Chem., 64 (24), 8197 (2000).
  • S. Kantham. Int. J. Pharm. Sci. Res. 3, 1284 (2011).
  • A. K. Ghumare, B. V. Pawar, and S. S. Bhagwat, J. Surfactants. Deterg., 16, 85 (2013).
  • S. Bhagwat, A novel amido-amine and glycerol based compound and its process of preparation, Nov. 28 2013. WO Patent App. PCT/IN2013/000,258.
  • D. Das, S. Roy, R. N. Mitra, A. Dasgupta, and P. K. Das, Chem. Eur. J., 11 (17), 4881 (2005).
  • Q. Zhang, Z. Gao, F. Xu, S. Tai, X. Liu, S. Mo, and F. Niu, Langmuir, 28 (33), 11979 (2012).
  • M. S. Bakshi, J. Colloid Interface Sci., 227(1), 78 (2000).
  • M. D. Emam, A. N. Nabel and M. R. Marwa, J. Surfactants Deterg., 16 (5) 723 (2013).
  • D. Das, S.Roy, R. N. Mitra, A. Dasgupta, and P. K. Das, Chem. Eur. J., 11, 4881 (2005).
  • D. Kwasniewska, K. Staszak, D. W. R. Zielinski, J. Surfactants Deterg., 18, 477 (2015).
  • Q. Zhang, Z. Gao, F. Xu, S. Tai, X. Liu, S. Mo, and F. Niu, Langmuir, 28, 11979 (2012).
  • M. K. Lalitha, Manual on antimicrobial susceptibility testing, Perform Stand Antimicrobial Test Twelfth Inf Suppl., 6 pp 7-14 (2004).
  • R. Zana, J. Colloid Interface Sci., 78 (2), 330 (1980).

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  • Solvent Free Synthesis, Characterization and Evaluation of Dimethylaminopropylamine based Double Tailed Amidoamine Cationic Surfactant

Abstract Views: 268  |  PDF Views: 11

Authors

Kumudini Aher
Department of Chemical Engineering, Institute of Chemical Technology, Mumbai - 400019, India
Sunil S. Bhagwat
Department of Chemical Engineering, Institute of Chemical Technology, Mumbai - 400019, Maharashtra, India

Abstract


Lauramidopropyl dimethylamine was quaternised using Lauryl Bromide to synthesize a double chain cationic surfactant. The surfactant was obtained in good yield without the use of any solvent. Amidoamine cationic surfactant chemical structure was analyzed using mass spectroscopic technique. The physicochemical properties of the amidoamine surfactant were calculated from surface tension and conductance measurements giving a critical micelle concentration of 8.04 × 10-3 mM which is quite lower than conventional surfactants. The amidoamine also exhibits a good foaming ability and wettability. The amidoamine cationic surfactant was evaluated for efficacy against different microorganisms and the results show that it has good antimicrobial activity against both Gram positive and Gram negative bacteria.

Keywords


Amidoamine, Critical Micelle Concentration, Quaternization, Surfactant, Synthesis.

References





DOI: https://doi.org/10.18311/jsst%2F2018%2F18083