Mineralogical and Chemical Characteristics of Complexly-Zoned Columbite-Tantalite from the Rare Metal Pegmatites of Southern Karnataka

Detailed mineralogical and chemical studies by EPMA on the Nb-Ta minerals from the rare metal pegmatites of southern Karnataka have revealed wide compositional variations, and the presence of some new minerals like tapiolite and microlite, hitherto unreported from these pegmatites. Back scattered electron (BSE) images have indicated complex zoning patterns such as oscillatory, patchy and/or their combinations, associated with replacement of columbite-tantalite by microlite, manifested by the variations of Nb₂O₅, Ta₂O₅, FeO and MnO. Such features, although known from a few rare meral pegmatites of the world, are being recorded here for the first time in India. Oscillatory zones in columbite-tantalites are manifested as alternating dark and light grey coloured bands, of which darker bands are Nb-rich (30-300 μM thick) and lighter bands are Ta-rich (125-450 μm thick). The wider zones may, in turn, consist of a group of very fine sub-zones (1-50 μm) of slightly varying composition: Patchy zoned crystals exhibit corroded remnants of early formed columbite-tantalite (with 39.73-44.02% Ta₂O₅), surrounded by later formed zones which are enriched in Ta₂O₅ (up to 50.99 %) in columbite-tantalite leading to the formation of microlite containing up to 73.4% Ta₂O₅. The zoning of the columbite-tantalites has been attributed to periodic changes in the composition of the major components such as Nb, Ta, Fe and Mn in the pegmatite fluid system, apparently influenced by the late stage fractionation of volatiles. This ultimately generated fluids rich in Ta and Na, resulting in resorption and replacement with patchy zoning of early formed, zoned columbite-tantalites.