Open Access Open Access  Restricted Access Subscription Access

Fly Ash/Slag Geopolymer Technology Development and Deployment in Construction and Infrastructure Industry:India’s Perspective


Affiliations
1 School of Business, PRIST University, Thanjavur-613403, Tamil Nadu, India
2 Department of Chemistry, SRM University, Kancheepuram District-603203, Tamil Nadu, India
3 Center for Advanced Concrete Research, SRM University, Kancheepuram District-603203, Tamil Nadu, India
 

India is fast shifting from the image of agrarian economy to industrial economy. While the total Indian Economy is of 152.51 lakh Crore rupees, the construction sector contribution alone to the national GDP is 10,64,068 Crore rupees. Construction and infrastructure industry exerts a lot of environmental pressure by consuming natural assets and the cement production is energy intensive. Cement that production is responsible for around 10% of global CO2 emissions. Like other countries with emerging economies, India faces the dual challenge of reconciling its rapid economic growth with a pressing need to address climate change. This paper addresses on the innovation in the Low carbon foot print material, Geopolymers, alternatives to Portland cement that show similar mechanical properties that provide new incentives to address the climate change. In India, geopolymer technology is still confined at laboratory research and development levels. Beyond research, this new material technology has to be crossed in transition from scientific discovery from laboratory to innovation and wide scale deployment. This paper centers on the feasibility of geopolymer production from the industrial by products: Fly ash/Slag from resources available and its application acceptance in India for the present and the future. The key drivers for uptake of geopolymer technology are the need of stakeholder’s initiative, development of knowledge base, technical/equipment providers and practical standards. Strategy and implementation plan at national level is required for promotion of green materials and replacement of high embodied energy materials with lower one.

Keywords

Geopolymer, Fly Ash, Indian Economy, CO2 Emission, Construction Industry.
User
Notifications
Font Size

  • CW, 2015. The Skill Gap, Hiranandani, N. Construction World, Jan-2015.
  • Economic-Survey: FY 2010-11, 2015-16., 2016-17
  • https://www.ibef.org/industry/real-estate-india.aspx.
  • Reports by india brand equity foundation on real estate,cementhttps://www.ibef.org/download/Cement-June-2017, www.ibef.org. DIPP, TechSci Research
  • Cement Technology Roadmap 2009 (International Energy Agency and World Business Council of Sustainable Development, 2009); http://go.nature.com/jQLKa7 .The technology papers at www.wbcsdcement.org/technology
  • Cement Statistics and Information 2015 (United States Geological Survey, 2015); http://go.nature.com/IqaKnt.
  • Pahuja, N., N. Pandey, K., Mandal, and Bandyopadhyay, C. 2014. “GHG Mitigation in India: An Overview of the Current Policy Landscape.” Working Paper. Washington, DC: World Resources Institute. Available online at http://www.wri. org/publication/ghg-mitigation-ind-policy.http://planningcommission.nic.in
  • Mita Bhattacharya, HooiHooi Lean and Sankar Bhattacharya, Economic Growth, Coal Demand, Carbon Dioxide Emissions: Empirical Findings from India with Policy Implications Discussion Paper 47/14 , ISSN 1441-5429 Department Of Economics, Monash University.
  • Govindaraju, V.G.R., Tang, C.F. 2013. The dynamic links between CO2 emissions, economic growth and coal consumption in China and India. Applied Energy.104:310–318. DOI: http://dx.doi.org/10.1016/j.apenergy.2012.10.042
  • Technology Roadmap: Low carbon technology for the Indian Cement Industry’ (WBCSD, IEA, February 2013).
  • Low Carbon Strategies for Inclusive Growth: An Interim Report’ (Planning Commission, Government of India, May 2011.
  • Fonta, P., Mishra,A.K.,Chaturvedi,S K.,Pahuja,A.,Twigg,C., Trudeau,N., Tam,C ., KiranAnanth, P V.,2011. Reduction Potentials In The Indian Cement Industry – A Way Forward. WBCSD CSI Technical Papers.
  • Provis, J L., Bernal, S A. 2014.Geopolymers and related alkali-activated materials, Annu. Rev. Mater. Res. 44: 299–327.DOI: https://doi.org/10.1146/annurev-matsci-070813-113515
  • Provis, J L., Palomo, A., Shi, C.2015. Advances in understanding alkali-activated materials, Cem. Concr. Res.78A: 110–125.
  • Provis, J L., van Deventer.J S J. 2014.Alkali-activatedMaterials: State-of-the-Art Report, RILEMTC 224-AAM, Springer/RILEM, Dordrecht.
  • Shi, C., Qian, J. 2000. High performance cementing materials from industrial slags - a review,Resour. Conserv. Recycl. 29:195-207.
  • Shi, C., Fernandez-Jimenez, A., Palomo, A. 2011. New cements for the 21st century: the pursuit of an alternative to Portland cement, Cem. Concr. Res. 41:750-763.
  • Shi, C., Krivenko, P V., Roy, D M. 2006. Alkali-activated Cements and Concretes, Taylor & Francis, Abingdon, UK.
  • Wang, S D., Pu, X C., Scrivener, K L., Pratt, P L. 1995.Alkali-activated slag cement and concrete: a review of properties and problems, Adv. Cem. Res. 7: 93-102.
  • J. Davidovits, (2015) Geopolymer: Chemistry and Applications, 4th edition, Institut Geopolymere, Saint-Quentin, France.
  • Davidovits, J. Patents : Tailored geopolymer composite binders for cement and concerte applications; USA WO/2010/085537 b)Pervious concrete comprising of geopolymerisedpozzolianic ash binder USA WO/2010/030560 28/24. c)Geopolyer concrete and method of preparation and casting Austraila. WO/2005/049522. d)Geocomposite US/4349386; GEOPOLYMER INSTITUTE : www.geopolymer.org.
  • Van Deventer, J S J., Provis, J L., Duxson, P. 2012. Technical and commercial progress in the adoption of geopolymer cement, Miner. Eng. 29:89-104.
  • Duxson, P., Fernandez-Jimenez, A., Provis, J L., Lukey, G C., Palomo, A., Deventer,J S J.2006. Geopolymer technology: the current state of the art, J. Mater. Sci. 42:2917-2933.
  • Purdon, 1940. The action of alkalis on blast furnace slag, Journal of the Society Chemical Industry Transactions & Communication, London ,59:191-202.
  • GluchovskijV.D., Gruntosilikaty, Gosstrojizdat Kiev 1959, Patent USSR 245 627 (1967), Patent USSR 449894 (Patent appl. 1958, filled 1974).
  • Frantisek Skvara, 2007, Alkali Activated Materials Or Geopolymers , Ceramics − Silikáty 51: 173-177.
  • Zhang , Z H., Zhu, H J., Zhou, C H., Wang, H. 2016. Geopolymer from kaolin in China: An overview, Applied Clay Science 119: 31-41
  • Yang, N., 1996. Physical chemistry basis for the formation of alkaline cementitious material. Part 2. J. Chin. Ceram. Soc. 24: 459-465.
  • Yang, N., 1996. Physical chemistry basis for the formation of alkaline cementitious material. Part 1. J. Chin. Ceram. Soc. 24: 202-215.
  • Roy, D.M., 1999, Alkali-activated cements-Opportunities and challenges, Cement and Concrete Research 29: 249-254
  • Shi,C., Krivinko,P.V., Roy, D.M. 2006.Alkali activated cements and concretes. Abingdon, UK, Taylor and Francis, 177-219.
  • Duxson, P., Fernandez-Jimenez, A., Provis, J.L., Lukey, G.C., Palomo, A., van Deventer, J.S.J. 2007. Geopolymer technology: The current state of the art. Journal of Materials Science, 42: 291-293.
  • Hardijito, D., Rangan, B V. 2005, Development and Properties of Low Calcium Fly Ash-Based Geopolymer Concrete, Research report-GCI, Faculty of engineering, curtin university of technology, perth, Australia.
  • Pacheco-Torgal, F., Castro-Gomes, J., Jalali, S. 2008. Alkali-activated binders: a review. Part1&II,About materials and binders manufacture, Construction and Building Materials, 22:1305-1322
  • Komnitsas, K., Zaharaki, D. 2007.Geopolymerisation: a review and prospects for the minerals industry, Minerals Engineering, 20: 1261-1277.
  • Shi, A. Fernandez-Jimenez, A. Palomo, 2011, New cements for the 21st century: the pursuit of an alternative to Portland cement, Cement and Concrete Research, 41: 750-763.
  • Bligh, R., and Glasby, T. 2013. Development of Geopolymer Precast Floor panels for the Global Change Institute at University of Queensland. Proceedings Concrete Institute of Australia Biennial Conference, Concrete – Understanding Concrete, Gold Coast, Australia.
  • Buchwald, A.M., Ch. Kaps , M. Hohmann, 2003. Alkali-Activated Binders And Pozzolan Cement Binders - Compete Binder Reaction Or Two Sides Of The Same Story? In Proceeding of the 11th International conference on the chemistry ofcement,Durban,SouthAfrica.1238-1246.
  • Habert G, d’Espinosede Lacaillerie JB, Roussel JB. 2011. An environmental evaluation of geopolymer based concrete production: reviewing current research trends. J Clean Prod 19: 1229-1238.
  • Malone P.G, Randall C and Kirkpatrick T,(1985),Potential applications of alkali activated alumino silicate binders in military operations.GL-85-15.Geotechnical laboratory Department of Army, Washington DC.
  • Jannie S.J vanDeventer, John L.Provis, Peter Duxson, (2012), Technical and commercial progress in the adoption of Geopolymer Cement, Minerals Engineering,Vol.29,pp 89-104.
  • A. Palomo, M.W. Grutzeck, M.T. Blanco, 1999. Alkali-activated fly ashes. A Cement for the future, Cement Concrete Res., 29: 1323-1329.
  • Heath, A., Paine, K., Goodhew, S., Ramage, M. and Lawrence, M., 2013. The potential for using geopolymer concrete in the UK. Proceedings of the Institution of Civil Engineers: Construction Materials, 166:195-203.
  • Balaguru P, 1998, Geopolymer for protective coating of transportation infrastructures, Final report, FHWA.
  • EREZ Allouche, Louisiana Tech. university, (2009) Geopolymer concrete in a greener construction technology rising from the ash application,science and sustainability of coal ash, 23-29.
  • CSIRO 2008 ‘Geopolymers: building blocks of the future’, www.csiro.au/science/ps19e.html, accessed 24 January 2012. Associated in Smith, M., Hargroves, K., Desha, C., & Stasinopoulos, P. (2009) ‘Factor 5 in eco-cement: Zeobond Pty Ltd.’, ECOS,Magazine, www.ecosmagazine.com/?paper=EC149p21, accessed 24 January 2012.Wagners, (2012).
  • EFC: Earth Friendly Concrete, [online] Available at:http://www.wagnerscft.com.au/files/2613/4731/0397/Wagners-Earth-Friendly-Concrete.pdf [Accessed 3 December 2014]
  • Gourley, J.T. and Johnson, G.B., (2005) “Developments in Geopolymer Precast Concrete”, Proceedings of the International Workshop on Geopolymers and Geopolymer Concrete, Perth, Australia, http://www.claisse.info/Proceedings.htm.
  • Andrews-Phaedonod F, 2012,Reducing carbon foot print through the VicRoads,concrete in Australia,Vol.40(1), pp40-48
  • Tom Glasby, John Day, Russell Genrich, and James Aldred(2015) EFC Geopolymer Concrete Aircraft Pavements at Brisbane West Well camp Airport, Concrete Conference, Melbourne Australia 2015
  • Provis, John, van Deventer, Jannie (Eds.), 2014, Alkali activated material, state of art Report, RILEM TC- 224-AAM,ISBN 978-94-007-7671-5.
  • FHWA,(2010) Geopolymerconcrete,CPTPTechBrief, FHWA-HIF-10014,Washington DC.
  • Sanjay Kumar and Rakesh Kumar. (2015). Synergizing Red (mud) and grey(ASH) for greener production, Bauxite residue valorization and best practices, Leuven,Vol.5-7
  • Radhakrinshna, Venugopal K, Saslatti Vinod and Venumadhav T, (2015). Study on geopolymer masonry as sustainable building material, Journal of environmental research and development, Vol. 9 (3A), pp 925-932.
  • RajamaneN.P., M.C. Nataraja and R. Jeyalakshmi, 2014. Discussion on “Pozzolanic industrial waste based geopolymer concretes with low carbon footprint”, The Indian Concrete Journal, 88: 8, August, Special Issue on Future Cements, pp 45-46.
  • Kolli Ramujee et al, 2015. Performance characteristics of Geopolymer concrete, Indian concrete institute Journal (ICI), 16: 30-36.
  • Rajamane N. P., M C Nataraja, R. Jeyalakshmi and S Nithiyanantham, 2015, Greener durable concretes through geopolymerisation of blast furnace slag”, Materials Research Express, 2-5.
  • Qaisar, S. H., Ahmad, M. A. 2014, Production, Consumption and Future Challenges of Coal in India, International Journal of Current Engineering and Technology, 3437-3440.
  • Ministry of Coal Source: http://coal.nic.in/content/coal-reserves., www.iflyash.com, www.ntpc.co.in, www.cfarm.org. http://www.cbrienvis.nic.in/flyashscenario., Fly ash utilizationunit.DST-GOI
  • Bhattacharjee U, KandpalTC. 2002. Potential of fly utilization in India. Energy, 27:151-66.
  • Ahmaruzaman M. 2010. A review on the utilization of flyashProgress in energy and combustion science”, 36: 327-363.
  • Haque, M.E. 2013. Indian fly-ash: production and consumption scenario. International Journal of Waste Resources. (IJWR), 3(1), 22-25.
  • The Indian Steel Industry 2015, Key Reforms for a Brighter Future, A report by National council of applied research infor@ncaer.orgwww.ncaer.org.
  • Reports by India brand equity foundation on realestate,cementhttps://www.ibef.org/download/steel-June-2017, www.ibef.org. DIPP, TechSci Research
  • Glukhovsky V.D, Krivenko P.V 1988., Manufacture of concretes and structures from slag alkaline binders, Budivelnyk Publish, Kiev, Ukrain.
  • Brodho O A 1999, Experience of exploitation of alkaline cements concrete. Ed. Krivenko P., Proceedings of the second international conference on Alkaline Cements and Concrete. 657-684.
  • Davidovits , J, and Sawyer, J.L. 1985 US patent 4, 509,985., office U.S.P (ed) Pyrament Inc USA.
  • Malone P G, Randall C J, Kirkpartick T ,1985. Potential applications of alkali activated aluminosilicate binders in military operations. Geotechnical Laboratory Department of Army, GL 85-15.
  • Palomo A, Fernandez-Jimnenz a., Lopex-homrados C and Lleyda J.L 2007. Railway sleepers made of alkali activated fly ash concrete Rev . Ing. Construction 22, vol 2 PP 75-80. http://dx.doi.org/10.4067/S0718-50732007000200001.
  • Xu.H., Provis JL., van Deventer J.S.J and Krivnko p V .2008. Characterisation of slag concretes ACI Mater J vol 105 (2) pp 131-139.
  • Palomo A, Krivenko P Garcia-Lodeiro I, Kavelerova E., Malteseva O., Fernandez-Jimenez A., 2014. A review on alkaline activation: New analytical perspectives, Materials De Construction, Vol.64, pp.1-25, http://dx.doi.org/10.3989/mc.2014.00314.
  • J G.SANJAYAN.2017 Material technology research to structural design of geopolymer concrete. Mechanics of structures and materials XXIV. Proceedings of the 24th Australian conference,December2016.edited by HangHao, Chunwei Zhang., CRC press, Taylor & Francis group) pp 31-40.
  • The Ministry of Construction of Enterprises of the USSR. of Heavy Industry. Standard-Slag alkaline binders, Technical specifications OST 67-11-84., 1984, Moscow.
  • DSTU B V 2.7-181 (2009) Alkaline cement specifications National standard of Ukraine, Kiev.
  • ASTM International Standard Performance Specification of Hydraulic cement, West Conshokocken, 2010, (ASTM C c1157/C1157M).
  • British Standard Specification 2016. Alkali Activateed Cementitious materials and concrete-Specifications: PAS 8820-58.
  • Berndt ,M., Sanjayan J., Foster S.,Castel A.,Rajeev P.,Heidrich C 2015. Progress towards handbook for geopolymer concrete .,Concrete 2015.Proceedings of the Biennial Conference of the concrete Institute of Australia in conjunction with 69th RILEM week 30th August to 2nd September, 2015,Melbourne, Australia.
  • Andrews-Phaedonos F 2013, Vicroads guidelines. Sections 703-General concrete paving., Section 701-underground storm water drains., Section 705-Drainage pits.,Section 711-wire rope safety barrier.

Abstract Views: 688

PDF Views: 328




  • Fly Ash/Slag Geopolymer Technology Development and Deployment in Construction and Infrastructure Industry:India’s Perspective

Abstract Views: 688  |  PDF Views: 328

Authors

S. Radhakrishnan
School of Business, PRIST University, Thanjavur-613403, Tamil Nadu, India
R. Jeyalakshmi
Department of Chemistry, SRM University, Kancheepuram District-603203, Tamil Nadu, India
K. G. Selvan
School of Business, PRIST University, Thanjavur-613403, Tamil Nadu, India
N. Rajamane
Center for Advanced Concrete Research, SRM University, Kancheepuram District-603203, Tamil Nadu, India

Abstract


India is fast shifting from the image of agrarian economy to industrial economy. While the total Indian Economy is of 152.51 lakh Crore rupees, the construction sector contribution alone to the national GDP is 10,64,068 Crore rupees. Construction and infrastructure industry exerts a lot of environmental pressure by consuming natural assets and the cement production is energy intensive. Cement that production is responsible for around 10% of global CO2 emissions. Like other countries with emerging economies, India faces the dual challenge of reconciling its rapid economic growth with a pressing need to address climate change. This paper addresses on the innovation in the Low carbon foot print material, Geopolymers, alternatives to Portland cement that show similar mechanical properties that provide new incentives to address the climate change. In India, geopolymer technology is still confined at laboratory research and development levels. Beyond research, this new material technology has to be crossed in transition from scientific discovery from laboratory to innovation and wide scale deployment. This paper centers on the feasibility of geopolymer production from the industrial by products: Fly ash/Slag from resources available and its application acceptance in India for the present and the future. The key drivers for uptake of geopolymer technology are the need of stakeholder’s initiative, development of knowledge base, technical/equipment providers and practical standards. Strategy and implementation plan at national level is required for promotion of green materials and replacement of high embodied energy materials with lower one.

Keywords


Geopolymer, Fly Ash, Indian Economy, CO2 Emission, Construction Industry.

References