Open Access Open Access  Restricted Access Subscription Access

Impact Of COVID-19 Lockdown On Surface Ozone Build-up at an Urban Site In Western India Based On Photochemical Box Modelling


Affiliations
1 Space and Atmospheric Sciences Division, Physical Research Laboratory, Ahmedabad 380 009, India
2 Space Physics Laboratory, Vikram Sarabhai Space Centre, Thiruvananthapuram 695 022, India
 

Elevated OzOne (O3) near the earth’s surface causes adverse impacts On human health and vegetatiOn, besides impacting air chemistry and climate. Intense lOckdOwn tO cOntain the spread Of COrOnavirus disease 2019 (COVID-19) Offered a rare OppOrtunity tO delineate the anthrOpOgenic impact On urban O3 build-up. In this regard, we incOrpOrated ObservatiOns Of chemical species and envirOnmental cOnditiOns intO a phOtOchemical bOx mOdel (NCAR Master Mechanism) tO study the O3 changes at a semi-arid urban site in western India (Ahmedabad; 23°N, 72.6°E). In cOntrast with primary pOllutants, daytime O3 build-up is Observed tO be enhanced during the lOckdOwn by ~39%. MOdel, driven by lOwer nitrOgen Oxides (NOx) during the lOckdOwn, alsO simulated enhanced O3 (by ~41%) shOwing the rOle Of nOnlinear dependence Of O3 On NOx. Further, a sensitivity simulatiOn unravelled an impOrtant rOle Of the meteOrOlOgical changes in the O3 enhancement (by ~16%) during the lOckdOwn. The results highlight that the lOckdOwn impacts can be mOdulated prOfOundly by the cOmplex chemistry plus meteOrOlOgical changes, Offsetting the benefits Of lOwer precursOr levels in the cOntext Of O3 pOllutiOn.

Keywords

Air Quality, Atmospheric Chemistry, COVID-19, Trace Gases.
User
Notifications
Font Size

  • Lelieveld, J. et al., The contribution of outdoor air pollution sources to premature mortality on a global scale. Nature, 2015, 525, 367–371; https://doi.org/10.1038/nature15371.
  • Ghude, S. D. et al., Premature mortality in India due to PM2.5 and ozone exposure. Geophys. Res. Lett., 2016, 43, 4650–4658; doi:10.1002/2016GL068949.
  • Sharma, A., Ojha, N., Pozzer, A., Beig, G. and Gunthe, S. S., Revisiting the crop yield loss in India attributable to ozone. Atmos. Environ., 2019, X, 1:100008; doi:https://doi.org/10.1016/j.aeaoa. 2019.100008
  • Jacob, D., Introduction to Atmospheric Chemistry, Princeton University Press, New Jersey 1999; doi:10.2307/j.ctt7t8hg.
  • Coates, J., Mar, K., Ojha, N. and Butler, Tim., The influence of temperature on ozone production under varying NOx conditions – a modelling study. Atmos. Chem. Phys., 2016, 16, 11601–11615; 10.5194/acp-16-11601-2016.
  • Akimoto, H., Global air quality and pollution. Science, 2003, 302(5651), 1716–1719; doi:10.1126/science.1092666.
  • Ojha, N. et al., On the widespread enhancement in fine particulate matter across the Indo-Gangetic Plain towards winter. Sci. Rep., 2020, 10, 5862; https://doi.org/10.1038/s41598-020-62710-8.
  • Gunthe, S., Beig, G. and Sahu, L., Study of relationship between daily maxima in ozone and temperature in an urban site in India. Curr. Sci., 2016, 110, 1994–1999; 10.18520/cs/v110/i10/19941999.
  • Sahu, L., Tripathi, N. and Yadav, R., Contribution of biogenic and photochemical sources to ambient VOCs during winter to summer transition at a semi-arid urban site in India. Environ. Pollut., 2017; doi: 10.1016/j.envpol.2017.06.091.
  • Kumar, R., Naja, M., Pfister, G. G., Barth, M. C., Wiedinmyer, C. and Brasseur, G. P., Simulations over South Asia using the weather research and forecasting model with chemistry (WRF-Chem): chemistry evaluation and initial results. Geosci. Model Dev., 2012, 5, 619–648; https://doi.org/10.5194/gmd-5-619-2012.
  • Ojha, N. et al., Variabilities in ozone at a semi‐urban site in the Indo‐Gangetic Plain region: Association with the meteorology and regional processes. J. Geophys. Res., 2012, 117, D20301; doi:10.1029/2012JD017716.
  • Sharma, A., Ojha, N., Pozzer, A., Mar, K. A., Beig, G., Lelieveld, J. and Gunthe, S. S., WRF-Chem simulated surface ozone over south Asia during the pre-monsoon: effects of emission inventories and chemical mechanisms. Atmos. Chem. Phys., 2017, 17, 14393–14413; https://doi.org/10.5194/acp-17-14393-2017.
  • Madronich, S., Chemical evolution of gaseous air pollutants down-wind of tropical megacities: Mexico City case study. Atmos. Environ., 2006, 40, 6012–6018; 10.1016/j.atmosenv.2005. 08.047.
  • Girach, I. A. et al., The changes in near-surface ozone and precursors at two nearby tropical sites during annular solar eclipse of 15 January 2010. J. Geophys. Res., 2012, 117, D01303; http://dx.doi.org/10.1029/2011JD016521.
  • Schnell, J. L. et al., Exploring the relationship between surface PM2.5 and meteorology in Northern India. Atmos. Chem. Phys., 2018, 18, 10157–10175; https://doi.org/10.5194/acp-18-101572018
  • Technical Specifications for Continuous Ambient Air Quality Monitoring (CAAQM) Station (Real Time), 2019; https://cpcb.nic.in/report.php
  • Singh, V., Singh, S., Biswal, A., Kesarkar, A. P., Mor, S. and Ravindra, K., Diurnal and temporal changes in air pollution during COVID-19 strict lockdown over different regions of India. Environ. Pollut., 2020, 266(3), 2020; 115368, ISSN 0269-7491, https://doi.org/10.1016/j.envpol.2020.115368
  • Sahu, L. and Lal, S., Distributions of c2-c5 nmhcs and related trace gases at a tropical urban site in India. Atmos. Environ., 2006, 40(5), 880–891; doi:https://doi.org/10.1016/j.atmosenv.2005.10.021
  • Mallik, C., Lal, S. and Sethuraman, V., Trace gases at a semi-arid urban site in western India: variability and inter-correlations. J. Atmos. Chem., 2015, 72, 143–164; doi:10.1007/s10874-015-9311-7.
  • Chandra, N., Venkataramani, S., Lal, S., Patra, P., Ramonet, M., Lin, X. and Sharma, S., Observational evidence of high methane emissions over a city in western India. Atmos. Environ., 2019, 202, 41–52; doi:https://doi.org/10.1016/j.atmosenv.2019.01.007.
  • Chutia, L. et al., Distribution of volatile organic compounds over Indian subcontinent during winter: Wrf-chem simulation versus observations. Environ. Pollut., 2019, 252, 256–269; doi:10.1016/j.envpol.2019.05.097.
  • Oltmans, S. J. and Levy, H., Surface ozone measurements from a global network. Atmos. Environ., 1994, 28(1), 9–24; https://doi.org/10.1016/1352-2310(94)90019-1.
  • Lal, S., Naja, M. and Subbaraya, B., Seasonal variations in surface ozone and its precursors over an urban site in India. Atmos. Environ., 2000, 34(17), 2713–2724; doi:https://doi.org/10.1016/ S1352-2310(99)00510-5
  • Ojha, N. et al., Surface ozone in the Doon Valley of the Himalayan foothills during spring. Environ. Sci. Pollut. Res., 2019, 26, 19155–19170; https://doi.org/10.1007/s11356-019-05085-2
  • Duderstadt, K. A. et al., Photochemical production and loss rates of ozone at Sable Island, Nova Scotia during the North Atlantic Regional Experiment (NARE) 1993 summer intensive. J. Geophys. Res., 1998, 103, 13,531–13,555; doi:10.1029/98JD00397.

Abstract Views: 217

PDF Views: 81




  • Impact Of COVID-19 Lockdown On Surface Ozone Build-up at an Urban Site In Western India Based On Photochemical Box Modelling

Abstract Views: 217  |  PDF Views: 81

Authors

Meghna Soni
Space and Atmospheric Sciences Division, Physical Research Laboratory, Ahmedabad 380 009, India
Narendra Ojha
Space and Atmospheric Sciences Division, Physical Research Laboratory, Ahmedabad 380 009, India
Imran Girach
Space Physics Laboratory, Vikram Sarabhai Space Centre, Thiruvananthapuram 695 022, India

Abstract


Elevated OzOne (O3) near the earth’s surface causes adverse impacts On human health and vegetatiOn, besides impacting air chemistry and climate. Intense lOckdOwn tO cOntain the spread Of COrOnavirus disease 2019 (COVID-19) Offered a rare OppOrtunity tO delineate the anthrOpOgenic impact On urban O3 build-up. In this regard, we incOrpOrated ObservatiOns Of chemical species and envirOnmental cOnditiOns intO a phOtOchemical bOx mOdel (NCAR Master Mechanism) tO study the O3 changes at a semi-arid urban site in western India (Ahmedabad; 23°N, 72.6°E). In cOntrast with primary pOllutants, daytime O3 build-up is Observed tO be enhanced during the lOckdOwn by ~39%. MOdel, driven by lOwer nitrOgen Oxides (NOx) during the lOckdOwn, alsO simulated enhanced O3 (by ~41%) shOwing the rOle Of nOnlinear dependence Of O3 On NOx. Further, a sensitivity simulatiOn unravelled an impOrtant rOle Of the meteOrOlOgical changes in the O3 enhancement (by ~16%) during the lOckdOwn. The results highlight that the lOckdOwn impacts can be mOdulated prOfOundly by the cOmplex chemistry plus meteOrOlOgical changes, Offsetting the benefits Of lOwer precursOr levels in the cOntext Of O3 pOllutiOn.

Keywords


Air Quality, Atmospheric Chemistry, COVID-19, Trace Gases.

References





DOI: https://doi.org/10.18520/cs%2Fv120%2Fi2%2F376-381